γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes

Sean M. Smith, Gia L. Hoang, Rhitankar Pal, Mohammad O.Bani Khaled, Liberty S.W. Pelter, Xiao Cheng Zeng, James M. Takacs

Research output: Contribution to journalArticle

28 Scopus citations

Abstract

Directed catalytic asymmetric hydroborations of 1,1-disubstituted alkenes afford γ-dioxaborato amides and esters in high enantiomeric purity (90-95% ee).

Original languageEnglish (US)
Pages (from-to)12180-12182
Number of pages3
JournalChemical Communications
Volume48
Issue number100
DOIs
StatePublished - Nov 21 2012

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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