TY - JOUR
T1 - π-Conjugated Systems with Unique Electronic Structure
T2 - A Case of “Planarized” 1,3-Connected Polyarylmethyl Carbodianion and Stable Triplet Hydrocarbon Diradical
AU - Rajca, Andrzej
AU - Utamapanya, Suchada
PY - 1992/3/1
Y1 - 1992/3/1
N2 - The effect of “planarization” on π-conjugated 1,3-connected polyarylmethyls in connection with the electronic structure and magnetic properties is examined. The synthesis, ESR and UV-vis spectroscopy, voltammetry, and magnetic studies of triplet diradical 62· are reported. The corresponding dianion 62−, 2M+ (M = Li, K) is studied using NMR and UV-vis spectroscopy.
AB - The effect of “planarization” on π-conjugated 1,3-connected polyarylmethyls in connection with the electronic structure and magnetic properties is examined. The synthesis, ESR and UV-vis spectroscopy, voltammetry, and magnetic studies of triplet diradical 62· are reported. The corresponding dianion 62−, 2M+ (M = Li, K) is studied using NMR and UV-vis spectroscopy.
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U2 - 10.1021/jo00032a030
DO - 10.1021/jo00032a030
M3 - Article
AN - SCOPUS:0010525501
SN - 0022-3263
VL - 57
SP - 1760
EP - 1767
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
IS - 6
ER -