2,4-dichlorophenyl 4-toluenesulfonate: Supramolecular aggregation through C-H⋯O, C-H⋯Cl, C-H⋯π and π⋯π interactions

Nagarajan Vembu; Maruthai Nallu; Jered Garrison; Wiley J. Youngs

doi:10.1107/S160053680301208X

2,4-dichlorophenyl 4-toluenesulfonate: Supramolecular aggregation through C-H⋯O, C-H⋯Cl, C-H⋯π and π⋯π interactions

Nagarajan Vembu, Maruthai Nallu, Jered Garrison, Wiley J. Youngs

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

In the crystal structure of the title molecule, C₁₃H ₁₀Cl₂O₃S, the dihedral angle between the mean planes of the 4-tolyl and 2,4-dichlorophenyl rings is 43.92 (4)°. There are weak C-H⋯O hydrogen bonds, which generate rings of motifs S(5), S(6), R₁²(4), R₂¹(6) and R ₂²(8). The supramolecular aggregation is completed by the presence of C-H⋯Cl, C-H⋯-π and π⋯π interactions.

Original language	English (US)
Pages (from-to)	o939-o941
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	7
DOIs	https://doi.org/10.1107/S160053680301208X
State	Published - Jul 2003
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "2,4-dichlorophenyl 4-toluenesulfonate: Supramolecular aggregation through C-H⋯O, C-H⋯Cl, C-H⋯π and π⋯π interactions",

abstract = "In the crystal structure of the title molecule, C13H 10Cl2O3S, the dihedral angle between the mean planes of the 4-tolyl and 2,4-dichlorophenyl rings is 43.92 (4)°. There are weak C-H⋯O hydrogen bonds, which generate rings of motifs S(5), S(6), R12(4), R21(6) and R 22(8). The supramolecular aggregation is completed by the presence of C-H⋯Cl, C-H⋯-π and π⋯π interactions.",

author = "Nagarajan Vembu and Maruthai Nallu and Jered Garrison and Youngs, {Wiley J.}",

year = "2003",

month = jul,

doi = "10.1107/S160053680301208X",

language = "English (US)",

volume = "59",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

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TY - JOUR

T1 - 2,4-dichlorophenyl 4-toluenesulfonate

T2 - Supramolecular aggregation through C-H⋯O, C-H⋯Cl, C-H⋯π and π⋯π interactions

AU - Vembu, Nagarajan

AU - Nallu, Maruthai

AU - Garrison, Jered

AU - Youngs, Wiley J.

PY - 2003/7

Y1 - 2003/7

N2 - In the crystal structure of the title molecule, C13H 10Cl2O3S, the dihedral angle between the mean planes of the 4-tolyl and 2,4-dichlorophenyl rings is 43.92 (4)°. There are weak C-H⋯O hydrogen bonds, which generate rings of motifs S(5), S(6), R12(4), R21(6) and R 22(8). The supramolecular aggregation is completed by the presence of C-H⋯Cl, C-H⋯-π and π⋯π interactions.

AB - In the crystal structure of the title molecule, C13H 10Cl2O3S, the dihedral angle between the mean planes of the 4-tolyl and 2,4-dichlorophenyl rings is 43.92 (4)°. There are weak C-H⋯O hydrogen bonds, which generate rings of motifs S(5), S(6), R12(4), R21(6) and R 22(8). The supramolecular aggregation is completed by the presence of C-H⋯Cl, C-H⋯-π and π⋯π interactions.

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

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ER -

2,4-dichlorophenyl 4-toluenesulfonate: Supramolecular aggregation through C-H⋯O, C-H⋯Cl, C-H⋯π and π⋯π interactions

Abstract

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