A New Synthon for Optically Active Diene Hydroperoxides

Patrick Dussault, In Quen Lee, Scott Kreifels

Research output: Contribution to journalArticle

24 Scopus citations

Abstract

The olefination of an enzymatically derived γ-peroxy-α,β-unsaturated aldehyde (1) allows the synthesis of optically active diene hydroperoxides in high enantiomeric excess. The application of this method to the synthesis of 13(S)-hydroperoxy-9(Z), 11(E)-octadecadienoic acid methyl ester is presented.

Original languageEnglish (US)
Pages (from-to)4087-4089
Number of pages3
JournalJournal of Organic Chemistry
Volume56
Issue number13
DOIs
StatePublished - Jun 1 1991

ASJC Scopus subject areas

  • Organic Chemistry

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