Abstract
A “pillar-free”, highly porous metalloporphyrinic framework (UNLPF-1) exhibiting eclipsed porphyrin arrays has been constructed from an octacarboxylate ligand connected with paddlewheel secondary building units. UNLPF-1 possesses two types of open metal sites and exhibits an efficient selectivity toward capture of CO2 over N2.
Original language | English (US) |
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Pages (from-to) | 2828-2830 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 49 |
Issue number | 27 |
DOIs | |
State | Published - Mar 7 2013 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- General Chemistry
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry