A “pillar-free”, highly porous metalloporphyrinic framework exhibiting eclipsed porphyrin arrays

Jacob A. Johnson, Qipu Lin, Lai Chin Wu, Nasrat Obaidi, Zachary L. Olson, Tyler C. Reeson, Yu Sheng Chen, Jian Zhang

Research output: Contribution to journalArticle

37 Scopus citations

Abstract

A “pillar-free”, highly porous metalloporphyrinic framework (UNLPF-1) exhibiting eclipsed porphyrin arrays has been constructed from an octacarboxylate ligand connected with paddlewheel secondary building units. UNLPF-1 possesses two types of open metal sites and exhibits an efficient selectivity toward capture of CO2 over N2.

Original languageEnglish (US)
Pages (from-to)2828-2830
Number of pages3
JournalChemical Communications
Volume49
Issue number27
DOIs
StatePublished - Mar 7 2013

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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    Johnson, J. A., Lin, Q., Wu, L. C., Obaidi, N., Olson, Z. L., Reeson, T. C., Chen, Y. S., & Zhang, J. (2013). A “pillar-free”, highly porous metalloporphyrinic framework exhibiting eclipsed porphyrin arrays. Chemical Communications, 49(27), 2828-2830. https://doi.org/10.1039/c3cc00049d