Application of a high-resolution superconducting NMR probe in natural product structure determination

Timothy M. Logan; Nagarajan Murali; Guangshun Wang; Catherine Jolivet

doi:10.1002/(sici)1097-458x(199910)37:10<762::aid-mrc584>3.0.co;2-p

Application of a high-resolution superconducting NMR probe in natural product structure determination

Timothy M. Logan, Nagarajan Murali, Guangshun Wang, Catherine Jolivet

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The r.f. properties of a high-resolution NMR probehead constructed of epitaxial thin films of high-temperature superconducting ceramics are presented. Operating the probe transmit/receive elements at 25 K significantly decreases the thermal noise of the r.f. coils and increases the probe quality factor (Q), resulting in a substantial increase in the signal-to-noise ratio. The lineshape and r.f. transmission characteristics of this probe were investigated. The utility of this probe for natural product structure determination was demonstrated using selective 1D NOE difference spectra.

Original language	English (US)
Pages (from-to)	762-765
Number of pages	4
Journal	Magnetic Resonance in Chemistry
Volume	37
Issue number	10
DOIs	https://doi.org/10.1002/(sici)1097-458x(199910)37:10<762::aid-mrc584>3.0.co;2-p
State	Published - Oct 1999
Externally published	Yes

Keywords

H NMR, sensitivity
High-temperature superconducting probe
NMR
Natural products

ASJC Scopus subject areas

General Chemistry
General Materials Science

Access to Document

10.1002/(sici)1097-458x(199910)37:10<762::aid-mrc584>3.0.co;2-p

Cite this

@article{9232b5573f2141448b18f5b094d19f43,

title = "Application of a high-resolution superconducting NMR probe in natural product structure determination",

abstract = "The r.f. properties of a high-resolution NMR probehead constructed of epitaxial thin films of high-temperature superconducting ceramics are presented. Operating the probe transmit/receive elements at 25 K significantly decreases the thermal noise of the r.f. coils and increases the probe quality factor (Q), resulting in a substantial increase in the signal-to-noise ratio. The lineshape and r.f. transmission characteristics of this probe were investigated. The utility of this probe for natural product structure determination was demonstrated using selective 1D NOE difference spectra.",

keywords = "H NMR, sensitivity, High-temperature superconducting probe, NMR, Natural products",

author = "Logan, {Timothy M.} and Nagarajan Murali and Guangshun Wang and Catherine Jolivet",

year = "1999",

month = oct,

doi = "10.1002/(sici)1097-458x(199910)37:10<762::aid-mrc584>3.0.co;2-p",

language = "English (US)",

volume = "37",

pages = "762--765",

journal = "Magnetic Resonance in Chemistry",

issn = "0749-1581",

publisher = "John Wiley and Sons Ltd",

number = "10",

}

TY - JOUR

T1 - Application of a high-resolution superconducting NMR probe in natural product structure determination

AU - Logan, Timothy M.

AU - Murali, Nagarajan

AU - Wang, Guangshun

AU - Jolivet, Catherine

PY - 1999/10

Y1 - 1999/10

N2 - The r.f. properties of a high-resolution NMR probehead constructed of epitaxial thin films of high-temperature superconducting ceramics are presented. Operating the probe transmit/receive elements at 25 K significantly decreases the thermal noise of the r.f. coils and increases the probe quality factor (Q), resulting in a substantial increase in the signal-to-noise ratio. The lineshape and r.f. transmission characteristics of this probe were investigated. The utility of this probe for natural product structure determination was demonstrated using selective 1D NOE difference spectra.

AB - The r.f. properties of a high-resolution NMR probehead constructed of epitaxial thin films of high-temperature superconducting ceramics are presented. Operating the probe transmit/receive elements at 25 K significantly decreases the thermal noise of the r.f. coils and increases the probe quality factor (Q), resulting in a substantial increase in the signal-to-noise ratio. The lineshape and r.f. transmission characteristics of this probe were investigated. The utility of this probe for natural product structure determination was demonstrated using selective 1D NOE difference spectra.

KW - H NMR, sensitivity

KW - High-temperature superconducting probe

KW - NMR

KW - Natural products

UR - http://www.scopus.com/inward/record.url?scp=0033211737&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0033211737&partnerID=8YFLogxK

U2 - 10.1002/(sici)1097-458x(199910)37:10<762::aid-mrc584>3.0.co;2-p

DO - 10.1002/(sici)1097-458x(199910)37:10<762::aid-mrc584>3.0.co;2-p

M3 - Article

AN - SCOPUS:0033211737

SN - 0749-1581

VL - 37

SP - 762

EP - 765

JO - Magnetic Resonance in Chemistry

JF - Magnetic Resonance in Chemistry

IS - 10

ER -

Application of a high-resolution superconducting NMR probe in natural product structure determination

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this