Aqua(1,5,8,12-tetramethyl-1,4,8,11-tetraazacyclotetradecane-N,N′, N″,N‴)copper(II) Diperchlorate

Tahir H. Tahirov, Tian Huey Lu, Fen Ling Liao, Sue Lein Wang, Bor Hann Chen, Ta Yung Chi, Chung Sun Chung

Research output: Contribution to journalArticle

6 Scopus citations

Abstract

The CuII ion in the title compound, [Cu(C14H32N4)-(H2O)](ClO 4)2, is five-coordinate in a distorted square-pyramidal geometry, with the four N atoms of the macrocyclic ligand equatorial and the O atom of the aqua group axial. The tetradentate ligand adopts its most stable conformation with the two six-membered rings in chair conformations and the two five-membered rings in gauche conformations. The complex has a 1SR,4SR,8SR, 11SR configuration for the four chiral N-atom centers and a 5RS,12RS configuration for the two chiral C-atom centers.

Original languageEnglish (US)
Pages (from-to)2687-2689
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume52
Issue number11
DOIs
StatePublished - Nov 15 1996

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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