Aqua(1,5,8,12-tetramethyl-1,4,8,11-tetraazacyclotetradecane-N,N′, N″,N‴)copper(II) Diperchlorate

Tahir H. Tahirov; Tian Huey Lu; Fen Ling Liao; Sue Lein Wang; Bor Hann Chen; Ta Yung Chi; Chung Sun Chung

doi:10.1107/S0108270196007925

Aqua(1,5,8,12-tetramethyl-1,4,8,11-tetraazacyclotetradecane-N,N′, N″,N‴)copper(II) Diperchlorate

Tahir H. Tahirov, Tian Huey Lu, Fen Ling Liao, Sue Lein Wang, Bor Hann Chen, Ta Yung Chi, Chung Sun Chung

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The Cu^II ion in the title compound, [Cu(C₁₄H₃₂N₄)-(H₂O)](ClO ₄)₂, is five-coordinate in a distorted square-pyramidal geometry, with the four N atoms of the macrocyclic ligand equatorial and the O atom of the aqua group axial. The tetradentate ligand adopts its most stable conformation with the two six-membered rings in chair conformations and the two five-membered rings in gauche conformations. The complex has a 1SR,4SR,8SR, 11SR configuration for the four chiral N-atom centers and a 5RS,12RS configuration for the two chiral C-atom centers.

Original language	English (US)
Pages (from-to)	2687-2689
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	52
Issue number	11
DOIs	https://doi.org/10.1107/S0108270196007925
State	Published - Nov 15 1996
Externally published	Yes

ASJC Scopus subject areas

General Biochemistry, Genetics and Molecular Biology

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title = "Aqua(1,5,8,12-tetramethyl-1,4,8,11-tetraazacyclotetradecane-N,N′, N″,N‴)copper(II) Diperchlorate",

abstract = "The CuII ion in the title compound, [Cu(C14H32N4)-(H2O)](ClO 4)2, is five-coordinate in a distorted square-pyramidal geometry, with the four N atoms of the macrocyclic ligand equatorial and the O atom of the aqua group axial. The tetradentate ligand adopts its most stable conformation with the two six-membered rings in chair conformations and the two five-membered rings in gauche conformations. The complex has a 1SR,4SR,8SR, 11SR configuration for the four chiral N-atom centers and a 5RS,12RS configuration for the two chiral C-atom centers.",

author = "Tahirov, {Tahir H.} and Lu, {Tian Huey} and Liao, {Fen Ling} and Wang, {Sue Lein} and Chen, {Bor Hann} and Chi, {Ta Yung} and Chung, {Chung Sun}",

year = "1996",

month = nov,

day = "15",

doi = "10.1107/S0108270196007925",

language = "English (US)",

volume = "52",

pages = "2687--2689",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "11",

}

TY - JOUR

T1 - Aqua(1,5,8,12-tetramethyl-1,4,8,11-tetraazacyclotetradecane-N,N′, N″,N‴)copper(II) Diperchlorate

AU - Tahirov, Tahir H.

AU - Lu, Tian Huey

AU - Liao, Fen Ling

AU - Wang, Sue Lein

AU - Chen, Bor Hann

AU - Chi, Ta Yung

AU - Chung, Chung Sun

PY - 1996/11/15

Y1 - 1996/11/15

N2 - The CuII ion in the title compound, [Cu(C14H32N4)-(H2O)](ClO 4)2, is five-coordinate in a distorted square-pyramidal geometry, with the four N atoms of the macrocyclic ligand equatorial and the O atom of the aqua group axial. The tetradentate ligand adopts its most stable conformation with the two six-membered rings in chair conformations and the two five-membered rings in gauche conformations. The complex has a 1SR,4SR,8SR, 11SR configuration for the four chiral N-atom centers and a 5RS,12RS configuration for the two chiral C-atom centers.

AB - The CuII ion in the title compound, [Cu(C14H32N4)-(H2O)](ClO 4)2, is five-coordinate in a distorted square-pyramidal geometry, with the four N atoms of the macrocyclic ligand equatorial and the O atom of the aqua group axial. The tetradentate ligand adopts its most stable conformation with the two six-membered rings in chair conformations and the two five-membered rings in gauche conformations. The complex has a 1SR,4SR,8SR, 11SR configuration for the four chiral N-atom centers and a 5RS,12RS configuration for the two chiral C-atom centers.

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DO - 10.1107/S0108270196007925

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AN - SCOPUS:3242820680

SN - 0108-2701

VL - 52

SP - 2687

EP - 2689

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 11

ER -

Aqua(1,5,8,12-tetramethyl-1,4,8,11-tetraazacyclotetradecane-N,N′, N″,N‴)copper(II) Diperchlorate

Abstract

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