B(C6F5)3-promoted tandem silylation and intramolecular hydrosilylation: Diastereoselective synthesis of oxasilinanes and oxasilepanes

Roman Shchepin, Chunping Xu, Patrick Dussault

Research output: Contribution to journalArticlepeer-review

41 Scopus citations

Abstract

B(C6F5)3 promotes regio- and stereoselective cyclizations of unsaturated alkoxysilanes to generate oxasilinanes and oxasilepanes. The same products are available directly from alkenols via tandem silylation and hydrosilylation.

Original languageEnglish (US)
Pages (from-to)4772-4775
Number of pages4
JournalOrganic Letters
Volume12
Issue number21
DOIs
StatePublished - Nov 5 2010
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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