B(C6F5)3-promoted tandem silylation and intramolecular hydrosilylation: Diastereoselective synthesis of oxasilinanes and oxasilepanes

Roman Shchepin; Chunping Xu; Patrick Dussault

doi:10.1021/ol1018757

B(C₆F₅)₃-promoted tandem silylation and intramolecular hydrosilylation: Diastereoselective synthesis of oxasilinanes and oxasilepanes

Roman Shchepin, Chunping Xu, Patrick Dussault

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

B(C₆F₅)₃ promotes regio- and stereoselective cyclizations of unsaturated alkoxysilanes to generate oxasilinanes and oxasilepanes. The same products are available directly from alkenols via tandem silylation and hydrosilylation.

Original language	English (US)
Pages (from-to)	4772-4775
Number of pages	4
Journal	Organic Letters
Volume	12
Issue number	21
DOIs	https://doi.org/10.1021/ol1018757
State	Published - Nov 5 2010
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

Access to Document

10.1021/ol1018757

Cite this

@article{02eb0d4f3bfd4bc2bc4c71a196d78b0f,

title = "B(C6F5)3-promoted tandem silylation and intramolecular hydrosilylation: Diastereoselective synthesis of oxasilinanes and oxasilepanes",

abstract = "B(C6F5)3 promotes regio- and stereoselective cyclizations of unsaturated alkoxysilanes to generate oxasilinanes and oxasilepanes. The same products are available directly from alkenols via tandem silylation and hydrosilylation.",

author = "Roman Shchepin and Chunping Xu and Patrick Dussault",

year = "2010",

month = nov,

day = "5",

doi = "10.1021/ol1018757",

language = "English (US)",

volume = "12",

pages = "4772--4775",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "21",

}

TY - JOUR

T1 - B(C6F5)3-promoted tandem silylation and intramolecular hydrosilylation

T2 - Diastereoselective synthesis of oxasilinanes and oxasilepanes

AU - Shchepin, Roman

AU - Xu, Chunping

AU - Dussault, Patrick

PY - 2010/11/5

Y1 - 2010/11/5

N2 - B(C6F5)3 promotes regio- and stereoselective cyclizations of unsaturated alkoxysilanes to generate oxasilinanes and oxasilepanes. The same products are available directly from alkenols via tandem silylation and hydrosilylation.

AB - B(C6F5)3 promotes regio- and stereoselective cyclizations of unsaturated alkoxysilanes to generate oxasilinanes and oxasilepanes. The same products are available directly from alkenols via tandem silylation and hydrosilylation.

UR - http://www.scopus.com/inward/record.url?scp=78049522571&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=78049522571&partnerID=8YFLogxK

U2 - 10.1021/ol1018757

DO - 10.1021/ol1018757

M3 - Article

C2 - 20919715

AN - SCOPUS:78049522571

SN - 1523-7060

VL - 12

SP - 4772

EP - 4775

JO - Organic Letters

JF - Organic Letters

IS - 21

ER -

B(C₆F₅)₃-promoted tandem silylation and intramolecular hydrosilylation: Diastereoselective synthesis of oxasilinanes and oxasilepanes

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this