Broadly applicable synthesis of 1,2,4,5-tetraoxanes

Prasanta Ghorai; Patrick H. Dussault

doi:10.1021/ol8023874

Broadly applicable synthesis of 1,2,4,5-tetraoxanes

Prasanta Ghorai, Patrick H. Dussault

Chemistry

Research output: Contribution to journal › Article

62 Scopus citations

Abstract

Re ₂O ₇ is a mild and efficient catalyst for the high-yielding condensation of 1,1-dihydroperoxides with ketones or aldehydes to form 1,2,4,5-tetraoxanes, including targets not easily prepared via existing methodology. When applied in tandem with a recently reported Re(VII)-catalyzed synthesis of 1,1-dihydroperoxides, the reaction provides a high-yielding one-pot conversion of ketones or aldehydes to tetraoxanes.

Original language	English (US)
Pages (from-to)	213-216
Number of pages	4
Journal	Organic Letters
Volume	11
Issue number	1
DOIs	https://doi.org/10.1021/ol8023874
State	Published - Jan 1 2009

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

Access to Document

10.1021/ol8023874

Fingerprint Dive into the research topics of 'Broadly applicable synthesis of 1,2,4,5-tetraoxanes'. Together they form a unique fingerprint.

Cite this

Ghorai, P., & Dussault, P. H. (2009). Broadly applicable synthesis of 1,2,4,5-tetraoxanes. Organic Letters, 11(1), 213-216. https://doi.org/10.1021/ol8023874

@article{c6cc592b582548bb8dc3e985c5eacb49,

title = "Broadly applicable synthesis of 1,2,4,5-tetraoxanes",

abstract = "Re 2O 7 is a mild and efficient catalyst for the high-yielding condensation of 1,1-dihydroperoxides with ketones or aldehydes to form 1,2,4,5-tetraoxanes, including targets not easily prepared via existing methodology. When applied in tandem with a recently reported Re(VII)-catalyzed synthesis of 1,1-dihydroperoxides, the reaction provides a high-yielding one-pot conversion of ketones or aldehydes to tetraoxanes.",

author = "Prasanta Ghorai and Dussault, {Patrick H.}",

year = "2009",

month = jan,

day = "1",

doi = "10.1021/ol8023874",

language = "English (US)",

volume = "11",

pages = "213--216",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "1",

}

TY - JOUR

T1 - Broadly applicable synthesis of 1,2,4,5-tetraoxanes

AU - Ghorai, Prasanta

AU - Dussault, Patrick H.

PY - 2009/1/1

Y1 - 2009/1/1

N2 - Re 2O 7 is a mild and efficient catalyst for the high-yielding condensation of 1,1-dihydroperoxides with ketones or aldehydes to form 1,2,4,5-tetraoxanes, including targets not easily prepared via existing methodology. When applied in tandem with a recently reported Re(VII)-catalyzed synthesis of 1,1-dihydroperoxides, the reaction provides a high-yielding one-pot conversion of ketones or aldehydes to tetraoxanes.

AB - Re 2O 7 is a mild and efficient catalyst for the high-yielding condensation of 1,1-dihydroperoxides with ketones or aldehydes to form 1,2,4,5-tetraoxanes, including targets not easily prepared via existing methodology. When applied in tandem with a recently reported Re(VII)-catalyzed synthesis of 1,1-dihydroperoxides, the reaction provides a high-yielding one-pot conversion of ketones or aldehydes to tetraoxanes.

UR - http://www.scopus.com/inward/record.url?scp=59649099224&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=59649099224&partnerID=8YFLogxK

U2 - 10.1021/ol8023874

DO - 10.1021/ol8023874

M3 - Article

C2 - 19111060

AN - SCOPUS:59649099224

VL - 11

SP - 213

EP - 216

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 1

ER -