Bulk and interfacial properties of quadrupolar fluids

V. B. Warshavsky; X. C. Zeng

doi:10.1063/1.1495841

Bulk and interfacial properties of quadrupolar fluids

V. B. Warshavsky, X. C. Zeng

Chemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The vapor-liquid phase equilibria and planar interfacial properties of quadrupolar fluids were studied. The surface ordering, surface polarization, density profile and surface tension of quadrupolar fluids were determined. It was found that the interfacial molecular ordering can arise entirely due to quadrupole-quadrupole interactions. It was also found that the bulk-phase properties of the quadrupolar fluids satisfy the law of correspondence states.

Original language	English (US)
Pages (from-to)	3982-3991
Number of pages	10
Journal	Journal of Chemical Physics
Volume	117
Issue number	8
DOIs	https://doi.org/10.1063/1.1495841
State	Published - Aug 22 2002

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

Access to Document

10.1063/1.1495841

Cite this

@article{bdd90ebaee014630bc4fe76fa4dba2c7,

title = "Bulk and interfacial properties of quadrupolar fluids",

abstract = "The vapor-liquid phase equilibria and planar interfacial properties of quadrupolar fluids were studied. The surface ordering, surface polarization, density profile and surface tension of quadrupolar fluids were determined. It was found that the interfacial molecular ordering can arise entirely due to quadrupole-quadrupole interactions. It was also found that the bulk-phase properties of the quadrupolar fluids satisfy the law of correspondence states.",

author = "Warshavsky, {V. B.} and Zeng, {X. C.}",

year = "2002",

month = aug,

day = "22",

doi = "10.1063/1.1495841",

language = "English (US)",

volume = "117",

pages = "3982--3991",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "8",

}

TY - JOUR

T1 - Bulk and interfacial properties of quadrupolar fluids

AU - Warshavsky, V. B.

AU - Zeng, X. C.

PY - 2002/8/22

Y1 - 2002/8/22

N2 - The vapor-liquid phase equilibria and planar interfacial properties of quadrupolar fluids were studied. The surface ordering, surface polarization, density profile and surface tension of quadrupolar fluids were determined. It was found that the interfacial molecular ordering can arise entirely due to quadrupole-quadrupole interactions. It was also found that the bulk-phase properties of the quadrupolar fluids satisfy the law of correspondence states.

AB - The vapor-liquid phase equilibria and planar interfacial properties of quadrupolar fluids were studied. The surface ordering, surface polarization, density profile and surface tension of quadrupolar fluids were determined. It was found that the interfacial molecular ordering can arise entirely due to quadrupole-quadrupole interactions. It was also found that the bulk-phase properties of the quadrupolar fluids satisfy the law of correspondence states.

UR - http://www.scopus.com/inward/record.url?scp=0037158534&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037158534&partnerID=8YFLogxK

U2 - 10.1063/1.1495841

DO - 10.1063/1.1495841

M3 - Article

AN - SCOPUS:0037158534

SN - 0021-9606

VL - 117

SP - 3982

EP - 3991

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 8

ER -

Bulk and interfacial properties of quadrupolar fluids

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this