Bulk and interfacial properties of quadrupolar fluids

V. B. Warshavsky, X. C. Zeng

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

The vapor-liquid phase equilibria and planar interfacial properties of quadrupolar fluids were studied. The surface ordering, surface polarization, density profile and surface tension of quadrupolar fluids were determined. It was found that the interfacial molecular ordering can arise entirely due to quadrupole-quadrupole interactions. It was also found that the bulk-phase properties of the quadrupolar fluids satisfy the law of correspondence states.

Original languageEnglish (US)
Pages (from-to)3982-3991
Number of pages10
JournalJournal of Chemical Physics
Volume117
Issue number8
DOIs
StatePublished - Aug 22 2002

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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