TY - JOUR
T1 - Catalytic Iron-Mediated Triene Carbocyclizations
T2 - Stereoselective Five-Membered Ring Forming Carbocyclizations
AU - Takacs, James M.
AU - Myoung, Young Chan
AU - Anderson, Lawrence G.
PY - 1994/11/1
Y1 - 1994/11/1
N2 - The full details of investigations into the regiochemistry and stereochemistry of iron-catalyzed carbocyclizations of 2,7,9-decatriene derivatives to form five-membered carbocyclic ring systems are described. The roles of the allylic substituent, the alkene geometry, diene substitution, and the influence of resident stereogenic centers incorporated in the tether chain connecting the reacting 1,3-diene and alkene subunits are discussed.
AB - The full details of investigations into the regiochemistry and stereochemistry of iron-catalyzed carbocyclizations of 2,7,9-decatriene derivatives to form five-membered carbocyclic ring systems are described. The roles of the allylic substituent, the alkene geometry, diene substitution, and the influence of resident stereogenic centers incorporated in the tether chain connecting the reacting 1,3-diene and alkene subunits are discussed.
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U2 - 10.1021/jo00102a016
DO - 10.1021/jo00102a016
M3 - Article
AN - SCOPUS:0001281770
VL - 59
SP - 6928
EP - 6942
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
SN - 0022-3263
IS - 23
ER -