Abstract
The full details of investigations into the regiochemistry and stereochemistry of iron-catalyzed carbocyclizations of 2,7,9-decatriene derivatives to form five-membered carbocyclic ring systems are described. The roles of the allylic substituent, the alkene geometry, diene substitution, and the influence of resident stereogenic centers incorporated in the tether chain connecting the reacting 1,3-diene and alkene subunits are discussed.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 6928-6942 |
| Number of pages | 15 |
| Journal | Journal of Organic Chemistry |
| Volume | 59 |
| Issue number | 23 |
| DOIs | |
| State | Published - Nov 1 1994 |
ASJC Scopus subject areas
- Organic Chemistry
Fingerprint Dive into the research topics of 'Catalytic Iron-Mediated Triene Carbocyclizations: Stereoselective Five-Membered Ring Forming Carbocyclizations'. Together they form a unique fingerprint.
Cite this
Takacs, J. M., Myoung, Y. C., & Anderson, L. G. (1994). Catalytic Iron-Mediated Triene Carbocyclizations: Stereoselective Five-Membered Ring Forming Carbocyclizations. Journal of Organic Chemistry, 59(23), 6928-6942. https://doi.org/10.1021/jo00102a016