Catalytic Palladium-Mediated Tetraene Carbocyclizations: 1,2- and 1,4-Stereochemical Control in a Polycyclization Reaction

James M. Takacs; Sithamalli V. Chandramouli

doi:10.1021/jo00078a001

Catalytic Palladium-Mediated Tetraene Carbocyclizations: 1,2- and 1,4-Stereochemical Control in a Polycyclization Reaction

James M. Takacs, Sithamalli V. Chandramouli

Chemistry

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

The palladium-mediated intramolecular diene-to-diene coupling with intramolecular trapping provides a novel route for the stereoselective construction of two new rings via the net 1,4-addition of carbon and oxygen across an internal diene subunit.

Original language	English (US)
Pages (from-to)	7315-7317
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	58
Issue number	26
DOIs	https://doi.org/10.1021/jo00078a001
State	Published - Dec 17 1993

ASJC Scopus subject areas

Organic Chemistry

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@article{b7ef2256cb544d9a950eb49984f7c9c8,

title = "Catalytic Palladium-Mediated Tetraene Carbocyclizations: 1,2- and 1,4-Stereochemical Control in a Polycyclization Reaction",

abstract = "The palladium-mediated intramolecular diene-to-diene coupling with intramolecular trapping provides a novel route for the stereoselective construction of two new rings via the net 1,4-addition of carbon and oxygen across an internal diene subunit.",

author = "Takacs, {James M.} and Chandramouli, {Sithamalli V.}",

year = "1993",

month = dec,

day = "17",

doi = "10.1021/jo00078a001",

language = "English (US)",

volume = "58",

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journal = "Journal of Organic Chemistry",

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publisher = "American Chemical Society",

number = "26",

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T1 - Catalytic Palladium-Mediated Tetraene Carbocyclizations

T2 - 1,2- and 1,4-Stereochemical Control in a Polycyclization Reaction

AU - Takacs, James M.

AU - Chandramouli, Sithamalli V.

PY - 1993/12/17

Y1 - 1993/12/17

N2 - The palladium-mediated intramolecular diene-to-diene coupling with intramolecular trapping provides a novel route for the stereoselective construction of two new rings via the net 1,4-addition of carbon and oxygen across an internal diene subunit.

AB - The palladium-mediated intramolecular diene-to-diene coupling with intramolecular trapping provides a novel route for the stereoselective construction of two new rings via the net 1,4-addition of carbon and oxygen across an internal diene subunit.

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U2 - 10.1021/jo00078a001

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M3 - Article

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 26

ER -

Catalytic Palladium-Mediated Tetraene Carbocyclizations: 1,2- and 1,4-Stereochemical Control in a Polycyclization Reaction

Abstract

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