Catalytic palladium-mediated tetraene carbocyclizations: The efficient stereochemical control of newly formed methyl-bearing stereocenters

James M. Takacs; Sithamalli V. Chandramouli

doi:10.1016/0040-4039(94)88455-2

Catalytic palladium-mediated tetraene carbocyclizations: The efficient stereochemical control of newly formed methyl-bearing stereocenters

James M. Takacs, Sithamalli V. Chandramouli

Chemistry

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Certain tetraene substrates bearing a trisubstituted double bond as part of one of the diene subunits undergo palladium-catalyzed cascade cyclization to afford cyclized products in which a new methyl-bearing stereocenter is generated in a stereoselective fashion.

Original language	English (US)
Pages (from-to)	9165-9168
Number of pages	4
Journal	Tetrahedron Letters
Volume	35
Issue number	49
DOIs	https://doi.org/10.1016/0040-4039(94)88455-2
State	Published - Dec 5 1994

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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title = "Catalytic palladium-mediated tetraene carbocyclizations: The efficient stereochemical control of newly formed methyl-bearing stereocenters",

abstract = "Certain tetraene substrates bearing a trisubstituted double bond as part of one of the diene subunits undergo palladium-catalyzed cascade cyclization to afford cyclized products in which a new methyl-bearing stereocenter is generated in a stereoselective fashion.",

author = "Takacs, {James M.} and Chandramouli, {Sithamalli V.}",

year = "1994",

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T1 - Catalytic palladium-mediated tetraene carbocyclizations

T2 - The efficient stereochemical control of newly formed methyl-bearing stereocenters

AU - Takacs, James M.

AU - Chandramouli, Sithamalli V.

PY - 1994/12/5

Y1 - 1994/12/5

N2 - Certain tetraene substrates bearing a trisubstituted double bond as part of one of the diene subunits undergo palladium-catalyzed cascade cyclization to afford cyclized products in which a new methyl-bearing stereocenter is generated in a stereoselective fashion.

AB - Certain tetraene substrates bearing a trisubstituted double bond as part of one of the diene subunits undergo palladium-catalyzed cascade cyclization to afford cyclized products in which a new methyl-bearing stereocenter is generated in a stereoselective fashion.

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U2 - 10.1016/0040-4039(94)88455-2

DO - 10.1016/0040-4039(94)88455-2

M3 - Article

AN - SCOPUS:0028073054

SN - 0040-4039

VL - 35

SP - 9165

EP - 9168

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 49

ER -

Catalytic palladium-mediated tetraene carbocyclizations: The efficient stereochemical control of newly formed methyl-bearing stereocenters

Abstract

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