Comparison of the electronic structure of two polymers with strong dipole ordering

Jie Xiao; Luis G. Rosa; Matt Poulsen; D. Q. Feng; D. Sahadeva Reddy; James M. Takacs; Lei Cai; Jiandi Zhang; Stephen Ducharme; P. A. Dowben

doi:10.1088/0953-8984/18/13/L01

Comparison of the electronic structure of two polymers with strong dipole ordering

Jie Xiao, Luis G. Rosa, Matt Poulsen, D. Q. Feng, D. Sahadeva Reddy, James M. Takacs, Lei Cai, Jiandi Zhang, Stephen Ducharme, P. A. Dowben

Chemistry

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

Two different polymers, with large local electric dipoles, are compared: copolymers of polyvinylidene fluoride with trifluoroethylene [P(VDF-TrFE, 70%:30%)] and polymethylvinylidenecyanide (PMVC). While the different local point group symmetries play a key role, both crystalline polymers exhibit intra-molecular band structure, though the Brillouin zone critical points differ.

Original language	English (US)
Pages (from-to)	L155-L161
Journal	Journal of Physics Condensed Matter
Volume	18
Issue number	13
DOIs	https://doi.org/10.1088/0953-8984/18/13/L01
State	Published - Apr 5 2006

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics

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abstract = "Two different polymers, with large local electric dipoles, are compared: copolymers of polyvinylidene fluoride with trifluoroethylene [P(VDF-TrFE, 70%:30%)] and polymethylvinylidenecyanide (PMVC). While the different local point group symmetries play a key role, both crystalline polymers exhibit intra-molecular band structure, though the Brillouin zone critical points differ.",

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AU - Xiao, Jie

AU - Rosa, Luis G.

AU - Poulsen, Matt

AU - Feng, D. Q.

AU - Sahadeva Reddy, D.

AU - Takacs, James M.

AU - Cai, Lei

AU - Zhang, Jiandi

AU - Ducharme, Stephen

AU - Dowben, P. A.

PY - 2006/4/5

Y1 - 2006/4/5

N2 - Two different polymers, with large local electric dipoles, are compared: copolymers of polyvinylidene fluoride with trifluoroethylene [P(VDF-TrFE, 70%:30%)] and polymethylvinylidenecyanide (PMVC). While the different local point group symmetries play a key role, both crystalline polymers exhibit intra-molecular band structure, though the Brillouin zone critical points differ.

AB - Two different polymers, with large local electric dipoles, are compared: copolymers of polyvinylidene fluoride with trifluoroethylene [P(VDF-TrFE, 70%:30%)] and polymethylvinylidenecyanide (PMVC). While the different local point group symmetries play a key role, both crystalline polymers exhibit intra-molecular band structure, though the Brillouin zone critical points differ.

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Comparison of the electronic structure of two polymers with strong dipole ordering

Abstract

ASJC Scopus subject areas

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