Conversion of diamond-like carbon film from phenylcarbyne polymer under pulsed green laser irradiation

Su Mei Huang; Yong Feng Lu; Zhuo Sun

doi:10.1143/jjap.39.1154

Conversion of diamond-like carbon film from phenylcarbyne polymer under pulsed green laser irradiation

Su Mei Huang, Yong Feng Lu, Zhuo Sun

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The synthesis of diamond-like carbon (DLC) films at room temperature by Nd:YAG pulsed laser (532 nm) irradiation of a polymer precursor is presented. The structures of films with the laser fluence were investigated by Raman spectroscopy. The morphologies of the resulting samples were examined by scanning electron microscopy (SEM), and the mechanism of DLC phases converted from the polymer is discussed. Raman spectrum analysis and SEM results indicate that the polymer is converted into amorphous carbon (a-C:H) phases with fluence from 60 to 650 mJ/cm² and crystalline diamond in amorphous carbon matrix phases with fluence above 650 mJ/cm² by pulsed laser irradiation in an argon gas atmosphere. It is proposed that the conversion of DLC phases is related to the special diamond-like structure of the polymer, and the laser provides an efficient thermal source.

Original language	English (US)
Pages (from-to)	1154-1159
Number of pages	6
Journal	Japanese Journal of Applied Physics
Volume	39
Issue number	3 A
DOIs	https://doi.org/10.1143/jjap.39.1154
State	Published - 2000
Externally published	Yes

Keywords

Diamond
Polymer precursor
Pulsed laser
Pyrolysis

ASJC Scopus subject areas

General Engineering
General Physics and Astronomy

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10.1143/jjap.39.1154

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title = "Conversion of diamond-like carbon film from phenylcarbyne polymer under pulsed green laser irradiation",

abstract = "The synthesis of diamond-like carbon (DLC) films at room temperature by Nd:YAG pulsed laser (532 nm) irradiation of a polymer precursor is presented. The structures of films with the laser fluence were investigated by Raman spectroscopy. The morphologies of the resulting samples were examined by scanning electron microscopy (SEM), and the mechanism of DLC phases converted from the polymer is discussed. Raman spectrum analysis and SEM results indicate that the polymer is converted into amorphous carbon (a-C:H) phases with fluence from 60 to 650 mJ/cm2 and crystalline diamond in amorphous carbon matrix phases with fluence above 650 mJ/cm2 by pulsed laser irradiation in an argon gas atmosphere. It is proposed that the conversion of DLC phases is related to the special diamond-like structure of the polymer, and the laser provides an efficient thermal source.",

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journal = "Japanese Journal of Applied Physics",

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publisher = "Japan Society of Applied Physics",

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TY - JOUR

T1 - Conversion of diamond-like carbon film from phenylcarbyne polymer under pulsed green laser irradiation

AU - Huang, Su Mei

AU - Lu, Yong Feng

AU - Sun, Zhuo

PY - 2000

Y1 - 2000

N2 - The synthesis of diamond-like carbon (DLC) films at room temperature by Nd:YAG pulsed laser (532 nm) irradiation of a polymer precursor is presented. The structures of films with the laser fluence were investigated by Raman spectroscopy. The morphologies of the resulting samples were examined by scanning electron microscopy (SEM), and the mechanism of DLC phases converted from the polymer is discussed. Raman spectrum analysis and SEM results indicate that the polymer is converted into amorphous carbon (a-C:H) phases with fluence from 60 to 650 mJ/cm2 and crystalline diamond in amorphous carbon matrix phases with fluence above 650 mJ/cm2 by pulsed laser irradiation in an argon gas atmosphere. It is proposed that the conversion of DLC phases is related to the special diamond-like structure of the polymer, and the laser provides an efficient thermal source.

AB - The synthesis of diamond-like carbon (DLC) films at room temperature by Nd:YAG pulsed laser (532 nm) irradiation of a polymer precursor is presented. The structures of films with the laser fluence were investigated by Raman spectroscopy. The morphologies of the resulting samples were examined by scanning electron microscopy (SEM), and the mechanism of DLC phases converted from the polymer is discussed. Raman spectrum analysis and SEM results indicate that the polymer is converted into amorphous carbon (a-C:H) phases with fluence from 60 to 650 mJ/cm2 and crystalline diamond in amorphous carbon matrix phases with fluence above 650 mJ/cm2 by pulsed laser irradiation in an argon gas atmosphere. It is proposed that the conversion of DLC phases is related to the special diamond-like structure of the polymer, and the laser provides an efficient thermal source.

KW - Diamond

KW - Polymer precursor

KW - Pulsed laser

KW - Pyrolysis

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Conversion of diamond-like carbon film from phenylcarbyne polymer under pulsed green laser irradiation

Abstract

Keywords

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