Crystal Engineering in Two Dimensions: Design of Amphiphiles for Ordered Films

C. J. Eckhardt; N. M. Peachey; D. R. Swanson; J. H. Kim; J. Wang; R. A. Uphaus; G. P. Lutz; P. Beak

doi:10.1021/la00047a003

Crystal Engineering in Two Dimensions: Design of Amphiphiles for Ordered Films

C. J. Eckhardt, N. M. Peachey, D. R. Swanson, J. H. Kim, J. Wang, R. A. Uphaus, G. P. Lutz, P. Beak

Computer Science and Engineering

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The results of an experimental and calculative study of a new, rigidified amphiphile designed to form a well-ordered, two-dimensional Langmuir-Blodgett monolayer crystal are reported. The packing of the amphiphile is shown by atomic force microscopy to be closer to hexagonal than found for a stearic acid monolayer. The true planar space group is p1. The results essentially mirror those obtained from an atom-atom potential calculation of the packing of the amphiphile. The investigation demonstrates the utility of designing amphiphiles to “engineer” specific planar lattices.

Original language	English (US)
Pages (from-to)	2591-2594
Number of pages	4
Journal	Langmuir
Volume	8
Issue number	11
DOIs	https://doi.org/10.1021/la00047a003
State	Published - Nov 1 1992

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics
Surfaces and Interfaces
Spectroscopy
Electrochemistry

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10.1021/la00047a003

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abstract = "The results of an experimental and calculative study of a new, rigidified amphiphile designed to form a well-ordered, two-dimensional Langmuir-Blodgett monolayer crystal are reported. The packing of the amphiphile is shown by atomic force microscopy to be closer to hexagonal than found for a stearic acid monolayer. The true planar space group is p1. The results essentially mirror those obtained from an atom-atom potential calculation of the packing of the amphiphile. The investigation demonstrates the utility of designing amphiphiles to “engineer” specific planar lattices.",

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AU - Eckhardt, C. J.

AU - Peachey, N. M.

AU - Swanson, D. R.

AU - Kim, J. H.

AU - Wang, J.

AU - Uphaus, R. A.

AU - Lutz, G. P.

AU - Beak, P.

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N2 - The results of an experimental and calculative study of a new, rigidified amphiphile designed to form a well-ordered, two-dimensional Langmuir-Blodgett monolayer crystal are reported. The packing of the amphiphile is shown by atomic force microscopy to be closer to hexagonal than found for a stearic acid monolayer. The true planar space group is p1. The results essentially mirror those obtained from an atom-atom potential calculation of the packing of the amphiphile. The investigation demonstrates the utility of designing amphiphiles to “engineer” specific planar lattices.

AB - The results of an experimental and calculative study of a new, rigidified amphiphile designed to form a well-ordered, two-dimensional Langmuir-Blodgett monolayer crystal are reported. The packing of the amphiphile is shown by atomic force microscopy to be closer to hexagonal than found for a stearic acid monolayer. The true planar space group is p1. The results essentially mirror those obtained from an atom-atom potential calculation of the packing of the amphiphile. The investigation demonstrates the utility of designing amphiphiles to “engineer” specific planar lattices.

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Crystal Engineering in Two Dimensions: Design of Amphiphiles for Ordered Films

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