Design of tailored oxide-carbide coating on carbon fibers for a robust copper/carbon interphase

Loic Constantin, Lisha Fan, Qiming Zou, Benjamin Thomas, Jérôme Roger, Jean Marc Heintz, Catherine Debiemme-Chouvy, Bruno Mortainge, Yong Feng Lu, Jean Francois Silvain

Research output: Contribution to journalArticle

1 Scopus citations

Abstract

The lack of robust interphases between carbon and most metals prevent the exploration of the full scope potential of carbon-based metal matrix composites. Here, we demonstrated a scalable and straightforward way to produce strong interphase between copper (Cu) and carbon fibers (CFs) by designing a tailored titanium oxide-carbide coating (TiOy-TiCx) on CFs in a molten salt process. The oxide-carbide composition in the graded layer strongly depends on the coating temperature (800–950 °C). A coating with a high TiOy content obtained at a low coating temperature (800 °C) contributes to better molten-Cu wetting and strong adhesion energy between CFs and Cu during a subsequent exposure at 1200 °C. The Cu wetting angle for the TiOy-TiCx-CF sample obtained at 800 °C was ∼80° ± 5° with a Cu surface coverage of ∼50% versus ∼115° and ∼10% for the TiCx-CF sample made at 950 °C. The kinetic analysis of the coating process step by step suggests a growth rate limited by the mass-transfer through the coated layer. This method provides a novel approach to improve the thermal conductivity of Cu/C composite for thermal management applications.

Original languageEnglish (US)
Pages (from-to)607-614
Number of pages8
JournalCarbon
Volume158
DOIs
StatePublished - Mar 2020

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)

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    Constantin, L., Fan, L., Zou, Q., Thomas, B., Roger, J., Heintz, J. M., Debiemme-Chouvy, C., Mortainge, B., Lu, Y. F., & Silvain, J. F. (2020). Design of tailored oxide-carbide coating on carbon fibers for a robust copper/carbon interphase. Carbon, 158, 607-614. https://doi.org/10.1016/j.carbon.2019.11.032