Detecting weak interactions between Au- and gas molecules: A photoelectron spectroscopic and Ab initio study

Yi Gao; Wei Huang; Jeffrey Woodford; Lai Sheng Wang; Cheng Zeng Xiao

doi:10.1021/ja903043d

Detecting weak interactions between Au^- and gas molecules: A photoelectron spectroscopic and Ab initio study

Yi Gao, Wei Huang, Jeffrey Woodford, Lai Sheng Wang, Cheng Zeng Xiao

Chemistry

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37 Scopus citations

Abstract

(Figure Presented) We show that anion photoelectron spectroscopy can be a very sensitive probe for weak intermolecular interactions between gold anion and a noble-gas atom or other nonreactive molecule. High-level ab initio calculations support the measured trend of relatively weak intermolecular interactions among various gold anion?atom complexes. The interaction between Au^? and H₂O is much stronger, comparable to a strong hydrogen bond. The interaction between Au^? and O₂ is weaker than that between Au^? and a noble-gas atom (Ar, Kr, or Xe).

Original language	English (US)
Pages (from-to)	9484-9485
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	27
DOIs	https://doi.org/10.1021/ja903043d
State	Published - Jul 15 2009

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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title = "Detecting weak interactions between Au- and gas molecules: A photoelectron spectroscopic and Ab initio study",

abstract = "(Figure Presented) We show that anion photoelectron spectroscopy can be a very sensitive probe for weak intermolecular interactions between gold anion and a noble-gas atom or other nonreactive molecule. High-level ab initio calculations support the measured trend of relatively weak intermolecular interactions among various gold anion?atom complexes. The interaction between Au? and H2O is much stronger, comparable to a strong hydrogen bond. The interaction between Au? and O2 is weaker than that between Au? and a noble-gas atom (Ar, Kr, or Xe).",

author = "Yi Gao and Wei Huang and Jeffrey Woodford and Wang, {Lai Sheng} and Xiao, {Cheng Zeng}",

year = "2009",

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doi = "10.1021/ja903043d",

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volume = "131",

pages = "9484--9485",

journal = "Journal of the American Chemical Society",

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TY - JOUR

T1 - Detecting weak interactions between Au- and gas molecules

T2 - A photoelectron spectroscopic and Ab initio study

AU - Gao, Yi

AU - Huang, Wei

AU - Woodford, Jeffrey

AU - Wang, Lai Sheng

AU - Xiao, Cheng Zeng

PY - 2009/7/15

Y1 - 2009/7/15

N2 - (Figure Presented) We show that anion photoelectron spectroscopy can be a very sensitive probe for weak intermolecular interactions between gold anion and a noble-gas atom or other nonreactive molecule. High-level ab initio calculations support the measured trend of relatively weak intermolecular interactions among various gold anion?atom complexes. The interaction between Au? and H2O is much stronger, comparable to a strong hydrogen bond. The interaction between Au? and O2 is weaker than that between Au? and a noble-gas atom (Ar, Kr, or Xe).

AB - (Figure Presented) We show that anion photoelectron spectroscopy can be a very sensitive probe for weak intermolecular interactions between gold anion and a noble-gas atom or other nonreactive molecule. High-level ab initio calculations support the measured trend of relatively weak intermolecular interactions among various gold anion?atom complexes. The interaction between Au? and H2O is much stronger, comparable to a strong hydrogen bond. The interaction between Au? and O2 is weaker than that between Au? and a noble-gas atom (Ar, Kr, or Xe).

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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Detecting weak interactions between Au^- and gas molecules: A photoelectron spectroscopic and Ab initio study

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