Efficient conversion of bromofullerene to alkoxyfullerenes through either homolytic or heterolytic cleavage of C60-Br bond

Zhenshan Jia; Qianyan Zhang; Yuliang Li; Liangbing Gan; Bo Zheng; Gu Yuan; Shiwei Zhang; Daoben Zhu

doi:10.1016/j.tet.2007.06.070

Efficient conversion of bromofullerene to alkoxyfullerenes through either homolytic or heterolytic cleavage of C₆₀-Br bond

Zhenshan Jia, Qianyan Zhang, Yuliang Li, Liangbing Gan, Bo Zheng, Gu Yuan, Shiwei Zhang, Daoben Zhu

Pharmaceutical Science

Research output: Contribution to journal › Article

8 Scopus citations

Abstract

The bromine atom in a fullerene-mixed peroxide derivative is replaced by an alkoxyl group under visible light irradiation or in the presence of silver salt. Homolytic or heterolytic cleavage of the C₆₀-Br bond is proposed to explain the mechanism. The presence of oxygen is also a key factor in the photolysis reaction.

Original language	English (US)
Pages (from-to)	9120-9123
Number of pages	4
Journal	Tetrahedron
Volume	63
Issue number	37
DOIs	https://doi.org/10.1016/j.tet.2007.06.070
State	Published - Sep 10 2007

Keywords

Alkoxylation
Fullerene
Halogenation
Heterolysis
Homolysis

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tet.2007.06.070

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Jia, Z., Zhang, Q., Li, Y., Gan, L., Zheng, B., Yuan, G., Zhang, S., & Zhu, D. (2007). Efficient conversion of bromofullerene to alkoxyfullerenes through either homolytic or heterolytic cleavage of C₆₀-Br bond. Tetrahedron, 63(37), 9120-9123. https://doi.org/10.1016/j.tet.2007.06.070

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keywords = "Alkoxylation, Fullerene, Halogenation, Heterolysis, Homolysis",

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T1 - Efficient conversion of bromofullerene to alkoxyfullerenes through either homolytic or heterolytic cleavage of C60-Br bond

AU - Jia, Zhenshan

AU - Zhang, Qianyan

AU - Li, Yuliang

AU - Gan, Liangbing

AU - Zheng, Bo

AU - Yuan, Gu

AU - Zhang, Shiwei

AU - Zhu, Daoben

PY - 2007/9/10

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AB - The bromine atom in a fullerene-mixed peroxide derivative is replaced by an alkoxyl group under visible light irradiation or in the presence of silver salt. Homolytic or heterolytic cleavage of the C60-Br bond is proposed to explain the mechanism. The presence of oxygen is also a key factor in the photolysis reaction.

KW - Alkoxylation

KW - Fullerene

KW - Halogenation

KW - Heterolysis

KW - Homolysis

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