Efficient conversion of bromofullerene to alkoxyfullerenes through either homolytic or heterolytic cleavage of C60-Br bond

Zhenshan Jia; Qianyan Zhang; Yuliang Li; Liangbing Gan; Bo Zheng; Gu Yuan; Shiwei Zhang; Daoben Zhu

doi:10.1016/j.tet.2007.06.070

Efficient conversion of bromofullerene to alkoxyfullerenes through either homolytic or heterolytic cleavage of C₆₀-Br bond

Zhenshan Jia, Qianyan Zhang, Yuliang Li, Liangbing Gan, Bo Zheng, Gu Yuan, Shiwei Zhang, Daoben Zhu

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The bromine atom in a fullerene-mixed peroxide derivative is replaced by an alkoxyl group under visible light irradiation or in the presence of silver salt. Homolytic or heterolytic cleavage of the C₆₀-Br bond is proposed to explain the mechanism. The presence of oxygen is also a key factor in the photolysis reaction.

Original language	English (US)
Pages (from-to)	9120-9123
Number of pages	4
Journal	Tetrahedron
Volume	63
Issue number	37
DOIs	https://doi.org/10.1016/j.tet.2007.06.070
State	Published - Sep 10 2007
Externally published	Yes

Keywords

Alkoxylation
Fullerene
Halogenation
Heterolysis
Homolysis

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/j.tet.2007.06.070

Cite this

@article{0fc6464f2a064550805d864cbdab24b6,

title = "Efficient conversion of bromofullerene to alkoxyfullerenes through either homolytic or heterolytic cleavage of C60-Br bond",

abstract = "The bromine atom in a fullerene-mixed peroxide derivative is replaced by an alkoxyl group under visible light irradiation or in the presence of silver salt. Homolytic or heterolytic cleavage of the C60-Br bond is proposed to explain the mechanism. The presence of oxygen is also a key factor in the photolysis reaction.",

keywords = "Alkoxylation, Fullerene, Halogenation, Heterolysis, Homolysis",

author = "Zhenshan Jia and Qianyan Zhang and Yuliang Li and Liangbing Gan and Bo Zheng and Gu Yuan and Shiwei Zhang and Daoben Zhu",

note = "Funding Information: Financial support is provided by NNSFC (Grants 20232010, 20521202, and 20472003), the Ministry of Education of China and the Major State Basic Research Development Program (2006CB806201). ",

year = "2007",

month = sep,

day = "10",

doi = "10.1016/j.tet.2007.06.070",

language = "English (US)",

volume = "63",

pages = "9120--9123",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Limited",

number = "37",

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TY - JOUR

T1 - Efficient conversion of bromofullerene to alkoxyfullerenes through either homolytic or heterolytic cleavage of C60-Br bond

AU - Jia, Zhenshan

AU - Zhang, Qianyan

AU - Li, Yuliang

AU - Gan, Liangbing

AU - Zheng, Bo

AU - Yuan, Gu

AU - Zhang, Shiwei

AU - Zhu, Daoben

N1 - Funding Information: Financial support is provided by NNSFC (Grants 20232010, 20521202, and 20472003), the Ministry of Education of China and the Major State Basic Research Development Program (2006CB806201).

PY - 2007/9/10

Y1 - 2007/9/10

N2 - The bromine atom in a fullerene-mixed peroxide derivative is replaced by an alkoxyl group under visible light irradiation or in the presence of silver salt. Homolytic or heterolytic cleavage of the C60-Br bond is proposed to explain the mechanism. The presence of oxygen is also a key factor in the photolysis reaction.

AB - The bromine atom in a fullerene-mixed peroxide derivative is replaced by an alkoxyl group under visible light irradiation or in the presence of silver salt. Homolytic or heterolytic cleavage of the C60-Br bond is proposed to explain the mechanism. The presence of oxygen is also a key factor in the photolysis reaction.

KW - Alkoxylation

KW - Fullerene

KW - Halogenation

KW - Heterolysis

KW - Homolysis

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U2 - 10.1016/j.tet.2007.06.070

DO - 10.1016/j.tet.2007.06.070

M3 - Article

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VL - 63

SP - 9120

EP - 9123

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

IS - 37

ER -