Abstract
A new method for the synthesis of tricyclic benzobisoxazines, based upon silica gel-catalyzed formation of two 3,1-oxazine rings, is reported. The reversibility of the condensation reaction, forming an oxazine ring, allows for implementation of silica gel catalyzed ketone exchange in benzobisoxazine, thus enabling access to nonsymmetric derivatives of benzobisoxazines.
Original language | English (US) |
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Pages (from-to) | 1867-1869 |
Number of pages | 3 |
Journal | Journal of Organic Chemistry |
Volume | 72 |
Issue number | 5 |
DOIs | |
State | Published - Mar 2 2007 |
ASJC Scopus subject areas
- Organic Chemistry