Excimer–monomer switch: A reaction-based approach for selective detection of fluoride

Qiao Song; Angela Bamesberger; Lingyun Yang; Haley Houtwed; Haishi Cao

doi:10.1039/c4an00522h

Excimer–monomer switch: A reaction-based approach for selective detection of fluoride

Qiao Song, Angela Bamesberger, Lingyun Yang, Haley Houtwed, Haishi Cao

Chemistry

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

A N-aryl-1,8-naphthalimide based sensor (ES-1) bearing a trimethylsilyl ether has been synthesized by a two-step reaction for quantitative detection of fluoride (F⁻). ES-1 exhibited monomer/excimer emissions at 410 and 524 nm respectively in CH₂Cl₂. In the presence of F⁻, the desilylation of trimethylsilyl ether caused decay of the excimer emission as well as enhancement of the monomer emission to give a ratiometric signal. The fluoride-triggered desilylation showed a high reaction rate and high affinity to F⁻ over nine other interfering anions. ES-1 provided a novel fluorescence assay based on excimer–monomer switch of N-aryl-1,8-naphthalimide to quantitatively measure F⁻ with a detection limit of 0.133 ppm.

Original language	English (US)
Pages (from-to)	3588-3592
Number of pages	5
Journal	Analyst
Volume	139
Issue number	14
DOIs	https://doi.org/10.1039/c4an00522h
State	Published - Jun 16 2013

ASJC Scopus subject areas

Analytical Chemistry
Biochemistry
Environmental Chemistry
Spectroscopy
Electrochemistry

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abstract = "A N-aryl-1,8-naphthalimide based sensor (ES-1) bearing a trimethylsilyl ether has been synthesized by a two-step reaction for quantitative detection of fluoride (F−). ES-1 exhibited monomer/excimer emissions at 410 and 524 nm respectively in CH2Cl2. In the presence of F−, the desilylation of trimethylsilyl ether caused decay of the excimer emission as well as enhancement of the monomer emission to give a ratiometric signal. The fluoride-triggered desilylation showed a high reaction rate and high affinity to F− over nine other interfering anions. ES-1 provided a novel fluorescence assay based on excimer–monomer switch of N-aryl-1,8-naphthalimide to quantitatively measure F− with a detection limit of 0.133 ppm.",

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AU - Song, Qiao

AU - Bamesberger, Angela

AU - Yang, Lingyun

AU - Houtwed, Haley

AU - Cao, Haishi

PY - 2013/6/16

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AB - A N-aryl-1,8-naphthalimide based sensor (ES-1) bearing a trimethylsilyl ether has been synthesized by a two-step reaction for quantitative detection of fluoride (F−). ES-1 exhibited monomer/excimer emissions at 410 and 524 nm respectively in CH2Cl2. In the presence of F−, the desilylation of trimethylsilyl ether caused decay of the excimer emission as well as enhancement of the monomer emission to give a ratiometric signal. The fluoride-triggered desilylation showed a high reaction rate and high affinity to F− over nine other interfering anions. ES-1 provided a novel fluorescence assay based on excimer–monomer switch of N-aryl-1,8-naphthalimide to quantitatively measure F− with a detection limit of 0.133 ppm.

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Excimer–monomer switch: A reaction-based approach for selective detection of fluoride

Abstract

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