Experimentally evaluating the equilibrium stress in shear of glassy polycarbonate

Mehrdad Negahban, Ashwani Goel, Pierre Delabarre, Feng Ruqiang, Amy Dimick

Research output: Contribution to journalArticlepeer-review

11 Scopus citations


One group of models proposed for characterizing the mechanical response of glassy polymers is based on a structure that resembles finite plasticity. In most cases, a constitutive equation for stress is proposed, which depends on the elastic deformation gradient, supplemented by a flow rule for the plastic deformation, which depends on the "over stress," The over stress is a properly invariant difference between the stress and the back stress (equilibrium stress). The back stress represents conditions under which relaxation events should stop and the material should be able to carry an applied load indefinitely without a need to change the strain. Questions that arise in using these models are whether such equilibrium stresses exist, how can they be evaluated, and what experiments can be used to characterize the flow rule. One challenge in accurately evaluating the locus of equilibrium conditions is the fact that the relaxation process substantially slow down around these points, and, therefore, a method that does not directly require being at the equilibrium is desirable. Focusing on shear, a thermodynamic theory for characterizing the response of glassy polymers, similar to models currently used for this purpose, is developed, and using this model it is shown that one can set up a method to calculate the plastic strain rate. This method is based on evaluating the slope of stress-strain response under conditions of similar elastic and plastic strain, but different strain rates. Since the equilibrium stress occurs when the plastic strain rate goes to zero, the evaluated plastic strain rates allow evaluation of the needed information for developing the flow rule and obtaining the back stress. This method is used to evaluate the plastic strain rate and back stress at room temperature for polycarbonate. The evaluated results match well with results obtained by direct probing of the equilibrium stress, in which one searches for points at which the stress remains constant at a constant strain over long durations. The method proposed looks promising in evaluating the back stress of glassy polymers. The added advantage of this method is that it also provides a map of plastic strain rate and tangent modulus over a large range of loading conditions.

Original languageEnglish (US)
Pages (from-to)537-542
Number of pages6
JournalJournal of Engineering Materials and Technology
Issue number4
StatePublished - Oct 2006
Externally publishedYes


  • Back stress
  • Equilibrium stress
  • Glassy polymer
  • Plastic strain rate
  • Polycarbonate
  • Shear
  • Thermodynamics

ASJC Scopus subject areas

  • General Materials Science
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering


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