Facile control of the charge density and photocatalytic activity of an anionic indium porphyrin framework via in situ metalation

Jacob A. Johnson; Xu Zhang; Tyler C. Reeson; Yu Sheng Chen; Jian Zhang

doi:10.1021/ja5092672

Facile control of the charge density and photocatalytic activity of an anionic indium porphyrin framework via in situ metalation

Jacob A. Johnson, Xu Zhang, Tyler C. Reeson, Yu Sheng Chen, Jian Zhang

Research output: Contribution to journal › Article

107 Scopus citations

Abstract

An anionic indium porphyrin framework (UNLPF-10) consisting of rare Williams β-tetrakaidecahedral cages was constructed using an octatopic ligand linked with 4-connected [In(COO)₄]^- SBUs. Remarkably, the extent of indium metalation of porphyrin macrocycles in UNLPF-10 can be facilely tuned in situ depending on the M/L ratio during synthesis, resulting in a controllable framework charge density and photocatalytic activity toward the selective oxygenation of sulfides.

Original language	English (US)
Pages (from-to)	15881-15884
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	136
Issue number	45
DOIs	https://doi.org/10.1021/ja5092672
State	Published - Nov 12 2014

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja5092672

Fingerprint Dive into the research topics of 'Facile control of the charge density and photocatalytic activity of an anionic indium porphyrin framework via in situ metalation'. Together they form a unique fingerprint.

Cite this

@article{0d3da4c78573407da9497ff58e66f921,

title = "Facile control of the charge density and photocatalytic activity of an anionic indium porphyrin framework via in situ metalation",

abstract = "An anionic indium porphyrin framework (UNLPF-10) consisting of rare Williams β-tetrakaidecahedral cages was constructed using an octatopic ligand linked with 4-connected [In(COO)4]- SBUs. Remarkably, the extent of indium metalation of porphyrin macrocycles in UNLPF-10 can be facilely tuned in situ depending on the M/L ratio during synthesis, resulting in a controllable framework charge density and photocatalytic activity toward the selective oxygenation of sulfides.",

author = "Johnson, {Jacob A.} and Xu Zhang and Reeson, {Tyler C.} and Chen, {Yu Sheng} and Jian Zhang",

year = "2014",

month = nov,

day = "12",

doi = "10.1021/ja5092672",

language = "English (US)",

volume = "136",

pages = "15881--15884",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "45",

}

TY - JOUR

T1 - Facile control of the charge density and photocatalytic activity of an anionic indium porphyrin framework via in situ metalation

AU - Johnson, Jacob A.

AU - Zhang, Xu

AU - Reeson, Tyler C.

AU - Chen, Yu Sheng

AU - Zhang, Jian

PY - 2014/11/12

Y1 - 2014/11/12

N2 - An anionic indium porphyrin framework (UNLPF-10) consisting of rare Williams β-tetrakaidecahedral cages was constructed using an octatopic ligand linked with 4-connected [In(COO)4]- SBUs. Remarkably, the extent of indium metalation of porphyrin macrocycles in UNLPF-10 can be facilely tuned in situ depending on the M/L ratio during synthesis, resulting in a controllable framework charge density and photocatalytic activity toward the selective oxygenation of sulfides.

AB - An anionic indium porphyrin framework (UNLPF-10) consisting of rare Williams β-tetrakaidecahedral cages was constructed using an octatopic ligand linked with 4-connected [In(COO)4]- SBUs. Remarkably, the extent of indium metalation of porphyrin macrocycles in UNLPF-10 can be facilely tuned in situ depending on the M/L ratio during synthesis, resulting in a controllable framework charge density and photocatalytic activity toward the selective oxygenation of sulfides.

UR - http://www.scopus.com/inward/record.url?scp=84910008127&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84910008127&partnerID=8YFLogxK

U2 - 10.1021/ja5092672

DO - 10.1021/ja5092672

M3 - Article

C2 - 25341191

AN - SCOPUS:84910008127

VL - 136

SP - 15881

EP - 15884

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 45

ER -