Facile control of the charge density and photocatalytic activity of an anionic indium porphyrin framework via in situ metalation

Jacob A. Johnson; Xu Zhang; Tyler C. Reeson; Yu Sheng Chen; Jian Zhang

doi:10.1021/ja5092672

Facile control of the charge density and photocatalytic activity of an anionic indium porphyrin framework via in situ metalation

Jacob A. Johnson, Xu Zhang, Tyler C. Reeson, Yu Sheng Chen, Jian Zhang

Research output: Contribution to journal › Article › peer-review

113 Scopus citations

Abstract

An anionic indium porphyrin framework (UNLPF-10) consisting of rare Williams β-tetrakaidecahedral cages was constructed using an octatopic ligand linked with 4-connected [In(COO)₄]^- SBUs. Remarkably, the extent of indium metalation of porphyrin macrocycles in UNLPF-10 can be facilely tuned in situ depending on the M/L ratio during synthesis, resulting in a controllable framework charge density and photocatalytic activity toward the selective oxygenation of sulfides.

Original language	English (US)
Pages (from-to)	15881-15884
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	136
Issue number	45
DOIs	https://doi.org/10.1021/ja5092672
State	Published - Nov 12 2014

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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abstract = "An anionic indium porphyrin framework (UNLPF-10) consisting of rare Williams β-tetrakaidecahedral cages was constructed using an octatopic ligand linked with 4-connected [In(COO)4]- SBUs. Remarkably, the extent of indium metalation of porphyrin macrocycles in UNLPF-10 can be facilely tuned in situ depending on the M/L ratio during synthesis, resulting in a controllable framework charge density and photocatalytic activity toward the selective oxygenation of sulfides.",

author = "Johnson, {Jacob A.} and Xu Zhang and Reeson, {Tyler C.} and Chen, {Yu Sheng} and Jian Zhang",

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AU - Johnson, Jacob A.

AU - Zhang, Xu

AU - Reeson, Tyler C.

AU - Chen, Yu Sheng

AU - Zhang, Jian

PY - 2014/11/12

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AB - An anionic indium porphyrin framework (UNLPF-10) consisting of rare Williams β-tetrakaidecahedral cages was constructed using an octatopic ligand linked with 4-connected [In(COO)4]- SBUs. Remarkably, the extent of indium metalation of porphyrin macrocycles in UNLPF-10 can be facilely tuned in situ depending on the M/L ratio during synthesis, resulting in a controllable framework charge density and photocatalytic activity toward the selective oxygenation of sulfides.

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Facile control of the charge density and photocatalytic activity of an anionic indium porphyrin framework via in situ metalation

Abstract

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