Facile synthesis of azo-linked porous organic frameworks via reductive homocoupling for selective CO2 capture

Jingzhi Lu, Jian Zhang

Research output: Contribution to journalArticlepeer-review

117 Scopus citations

Abstract

A facile Zn-induced reductive homocoupling reaction was used to synthesize azo-linked porous organic frameworks (azo-POFs) from easily accessed nitro monomers. Azo-POF-2 exhibits the highest CO2/N2 selectivity of 76 at 273 K among all self-coupled azo-linked porous polymers. This journal is

Original languageEnglish (US)
Pages (from-to)13831-13834
Number of pages4
JournalJournal of Materials Chemistry A
Volume2
Issue number34
DOIs
StatePublished - Sep 14 2014

ASJC Scopus subject areas

  • General Chemistry
  • Renewable Energy, Sustainability and the Environment
  • General Materials Science

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