Generation and Release of OH Radicals from the Reaction of H2O with O2 over Soot

Guangzhi He, Jinzhu Ma, Biwu Chu, Renzhi Hu, Hao Li, Meng Gao, Yuan Liu, Yonghong Wang, Qingxin Ma, Pinhua Xie, Guoxian Zhang, Xiao Cheng Zeng, Joseph S. Francisco, Hong He

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

OH radicals in the air maintain the oxidizing power of the troposphere. A conventional view is that particulate matter (PM) in the atmosphere is a major sink of OH radicals, thereby lowering the oxidizing power of atmosphere in the event of high-level PM. By contrary, our joint experimental/theoretical study reveals a new mechanism for the generation of gaseous OH radicals by carbonaceous soot particles. We show that water and O2 react on carbonaceous surfaces and give rise to gaseous OH radicals under irradiation. With ample delocalized π electrons, carbonaceous surfaces enable the easy desorption of hydroxyl groups to produce gaseous OH radicals, evidenced by direct observation of the steady generation of OH radicals on a carbonaceous surface. Our results reveal a new chemical mechanism for the production of OH radicals.

Original languageEnglish (US)
Article numbere202201638
JournalAngewandte Chemie - International Edition
Volume61
Issue number21
DOIs
StatePublished - May 16 2022

Keywords

  • Carbonaceous Surface
  • OH Radicals
  • Soot
  • Surface Hydroxyls

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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