High-resolution studies of domain switching behavior in nanostructured ferroelectric polymers

Pankaj Sharma; Timothy J. Reece; Stephen Ducharme; Alexei Gruverman

doi:10.1021/nl200221z

High-resolution studies of domain switching behavior in nanostructured ferroelectric polymers

Pankaj Sharma, Timothy J. Reece, Stephen Ducharme, Alexei Gruverman

Physics & Physical Science

Research output: Contribution to journal › Article › peer-review

111 Scopus citations

Abstract

We have demonstrated an effective electrical control of polarization in the individual crystalline nanomesas of the ferroelectric polymer, poly(vinylidene fluoride)-trifluoroethylene (PVDF-TrFE) and its relation to the polymer structure. The mechanism of polarization reversal has been investigated via sub-10 nm real space imaging of domain pattern evolution under an applied electric field. The domain switching behavior revealed in PVDF-TrFE nanomesas is drastically different from that observed in inorganic solid-state crystalline ferroelectrics. The nanoscale features of the switching process include remote domain nucleation and spatially nonuniform wall velocity. Local switching spectroscopy and domain dynamics studies relate the observed switching features to a random-bond type disorder associated with defects in conformation and molecular packing.

Original language	English (US)
Pages (from-to)	1970-1975
Number of pages	6
Journal	Nano Letters
Volume	11
Issue number	5
DOIs	https://doi.org/10.1021/nl200221z
State	Published - May 11 2011

Keywords

Ferroelectric polymer
disorder
domain switching
piezoresponse force microscopy

ASJC Scopus subject areas

Bioengineering
General Chemistry
General Materials Science
Condensed Matter Physics
Mechanical Engineering

Access to Document

10.1021/nl200221z

Cite this

@article{0e1c15aa0cfc4448ae089921bb3fcd40,

title = "High-resolution studies of domain switching behavior in nanostructured ferroelectric polymers",

abstract = "We have demonstrated an effective electrical control of polarization in the individual crystalline nanomesas of the ferroelectric polymer, poly(vinylidene fluoride)-trifluoroethylene (PVDF-TrFE) and its relation to the polymer structure. The mechanism of polarization reversal has been investigated via sub-10 nm real space imaging of domain pattern evolution under an applied electric field. The domain switching behavior revealed in PVDF-TrFE nanomesas is drastically different from that observed in inorganic solid-state crystalline ferroelectrics. The nanoscale features of the switching process include remote domain nucleation and spatially nonuniform wall velocity. Local switching spectroscopy and domain dynamics studies relate the observed switching features to a random-bond type disorder associated with defects in conformation and molecular packing.",

keywords = "Ferroelectric polymer, disorder, domain switching, piezoresponse force microscopy",

author = "Pankaj Sharma and Reece, {Timothy J.} and Stephen Ducharme and Alexei Gruverman",

year = "2011",

month = may,

day = "11",

doi = "10.1021/nl200221z",

language = "English (US)",

volume = "11",

pages = "1970--1975",

journal = "Nano Letters",

issn = "1530-6984",

publisher = "American Chemical Society",

number = "5",

}

TY - JOUR

T1 - High-resolution studies of domain switching behavior in nanostructured ferroelectric polymers

AU - Sharma, Pankaj

AU - Reece, Timothy J.

AU - Ducharme, Stephen

AU - Gruverman, Alexei

PY - 2011/5/11

Y1 - 2011/5/11

N2 - We have demonstrated an effective electrical control of polarization in the individual crystalline nanomesas of the ferroelectric polymer, poly(vinylidene fluoride)-trifluoroethylene (PVDF-TrFE) and its relation to the polymer structure. The mechanism of polarization reversal has been investigated via sub-10 nm real space imaging of domain pattern evolution under an applied electric field. The domain switching behavior revealed in PVDF-TrFE nanomesas is drastically different from that observed in inorganic solid-state crystalline ferroelectrics. The nanoscale features of the switching process include remote domain nucleation and spatially nonuniform wall velocity. Local switching spectroscopy and domain dynamics studies relate the observed switching features to a random-bond type disorder associated with defects in conformation and molecular packing.

AB - We have demonstrated an effective electrical control of polarization in the individual crystalline nanomesas of the ferroelectric polymer, poly(vinylidene fluoride)-trifluoroethylene (PVDF-TrFE) and its relation to the polymer structure. The mechanism of polarization reversal has been investigated via sub-10 nm real space imaging of domain pattern evolution under an applied electric field. The domain switching behavior revealed in PVDF-TrFE nanomesas is drastically different from that observed in inorganic solid-state crystalline ferroelectrics. The nanoscale features of the switching process include remote domain nucleation and spatially nonuniform wall velocity. Local switching spectroscopy and domain dynamics studies relate the observed switching features to a random-bond type disorder associated with defects in conformation and molecular packing.

KW - Ferroelectric polymer

KW - disorder

KW - domain switching

KW - piezoresponse force microscopy

UR - http://www.scopus.com/inward/record.url?scp=79955881279&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=79955881279&partnerID=8YFLogxK

U2 - 10.1021/nl200221z

DO - 10.1021/nl200221z

M3 - Article

C2 - 21462936

AN - SCOPUS:79955881279

SN - 1530-6984

VL - 11

SP - 1970

EP - 1975

JO - Nano Letters

JF - Nano Letters

IS - 5

ER -

High-resolution studies of domain switching behavior in nanostructured ferroelectric polymers

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this