High-Spin Organic Diradical with Robust Stability

Nolan M. Gallagher; Jackson J. Bauer; Maren Pink; Suchada Rajca; Andrzej Rajca

doi:10.1021/jacs.6b05080

High-Spin Organic Diradical with Robust Stability

Nolan M. Gallagher, Jackson J. Bauer, Maren Pink, Suchada Rajca, Andrzej Rajca

Chemistry

Research output: Contribution to journal › Article › peer-review

88 Scopus citations

Abstract

Triplet ground-state organic molecules are interesting with respect to several emerging technologies but typically exhibit limited stability. We report two organic diradicals, one of which possesses a triplet ground state (2J/k_B = 234 ± 36 K) and robust stability at elevated temperatures. We are able to sublime this high-spin diradical under high vacuum at 140 °C with no significant decomposition.

Original language	English (US)
Pages (from-to)	9377-9380
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	138
Issue number	30
DOIs	https://doi.org/10.1021/jacs.6b05080
State	Published - Aug 3 2016

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/jacs.6b05080

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abstract = "Triplet ground-state organic molecules are interesting with respect to several emerging technologies but typically exhibit limited stability. We report two organic diradicals, one of which possesses a triplet ground state (2J/kB = 234 ± 36 K) and robust stability at elevated temperatures. We are able to sublime this high-spin diradical under high vacuum at 140 °C with no significant decomposition.",

author = "Gallagher, {Nolan M.} and Bauer, {Jackson J.} and Maren Pink and Suchada Rajca and Andrzej Rajca",

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AU - Rajca, Suchada

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AB - Triplet ground-state organic molecules are interesting with respect to several emerging technologies but typically exhibit limited stability. We report two organic diradicals, one of which possesses a triplet ground state (2J/kB = 234 ± 36 K) and robust stability at elevated temperatures. We are able to sublime this high-spin diradical under high vacuum at 140 °C with no significant decomposition.

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High-Spin Organic Diradical with Robust Stability

Abstract

ASJC Scopus subject areas

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