Abstract
Two non-interpenetrated zirconium metal-organic frameworks (Zr-MOFs), NPF-200 and NPF-201, were synthesized via the assembly of elongated tetrahedral linkers with Zr6 and Zr8 clusters. They represent the first examples of MOFs to have the β-UH3-like, 4,12,12T1 topology. Upon activation, NPF-200 exhibits the largest BET surface area (5463 m2 g-1) and void volume (81.6%) among all MOFs formed from tetrahedral ligands. Composed of negative-charged boron-centered tetrahedral linkers, NPF-201 is an anionic Zr-MOF which selectively uptakes photoactive [Ru(bpy)3]2+ for heterogeneous photo-oxidation of thioanisole.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 8380-8383 |
| Number of pages | 4 |
| Journal | Journal of the American Chemical Society |
| Volume | 138 |
| Issue number | 27 |
| DOIs | |
| State | Published - Jul 13 2016 |
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
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Zhang, X., Zhang, X., Johnson, J. A., Chen, Y. S., & Zhang, J. (2016). Highly Porous Zirconium Metal-Organic Frameworks with β-UH3-like Topology Based on Elongated Tetrahedral Linkers. Journal of the American Chemical Society, 138(27), 8380-8383. https://doi.org/10.1021/jacs.6b04608