TY - JOUR
T1 - Highly Porous Zirconium Metal-Organic Frameworks with β-UH3-like Topology Based on Elongated Tetrahedral Linkers
AU - Zhang, Xin
AU - Zhang, Xu
AU - Johnson, Jacob A.
AU - Chen, Yu Sheng
AU - Zhang, Jian
N1 - Funding Information:
The authors acknowledge the support from the University of Nebraska-Lincoln. ChemMatCARS Sector 15 is principally supported by the Divisions of Chemistry (CHE) and Materials Research (DMR), National Science Foundation, under grant no. NSF/CHE-1346572. Use of the APS, anOffice of Science User Facility operated for the U.S. DOE Office of Science by ANL, was supported under Contract No. DE-AC02-06CH11357.
PY - 2016/7/13
Y1 - 2016/7/13
N2 - Two non-interpenetrated zirconium metal-organic frameworks (Zr-MOFs), NPF-200 and NPF-201, were synthesized via the assembly of elongated tetrahedral linkers with Zr6 and Zr8 clusters. They represent the first examples of MOFs to have the β-UH3-like, 4,12,12T1 topology. Upon activation, NPF-200 exhibits the largest BET surface area (5463 m2 g-1) and void volume (81.6%) among all MOFs formed from tetrahedral ligands. Composed of negative-charged boron-centered tetrahedral linkers, NPF-201 is an anionic Zr-MOF which selectively uptakes photoactive [Ru(bpy)3]2+ for heterogeneous photo-oxidation of thioanisole.
AB - Two non-interpenetrated zirconium metal-organic frameworks (Zr-MOFs), NPF-200 and NPF-201, were synthesized via the assembly of elongated tetrahedral linkers with Zr6 and Zr8 clusters. They represent the first examples of MOFs to have the β-UH3-like, 4,12,12T1 topology. Upon activation, NPF-200 exhibits the largest BET surface area (5463 m2 g-1) and void volume (81.6%) among all MOFs formed from tetrahedral ligands. Composed of negative-charged boron-centered tetrahedral linkers, NPF-201 is an anionic Zr-MOF which selectively uptakes photoactive [Ru(bpy)3]2+ for heterogeneous photo-oxidation of thioanisole.
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U2 - 10.1021/jacs.6b04608
DO - 10.1021/jacs.6b04608
M3 - Article
C2 - 27341503
AN - SCOPUS:84978864759
VL - 138
SP - 8380
EP - 8383
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 27
ER -