Highly Porous Zirconium Metal-Organic Frameworks with β-UH3-like Topology Based on Elongated Tetrahedral Linkers

Xin Zhang; Xu Zhang; Jacob A. Johnson; Yu Sheng Chen; Jian Zhang

doi:10.1021/jacs.6b04608

Highly Porous Zirconium Metal-Organic Frameworks with β-UH₃-like Topology Based on Elongated Tetrahedral Linkers

Xin Zhang, Xu Zhang, Jacob A. Johnson, Yu Sheng Chen, Jian Zhang

Research output: Contribution to journal › Article › peer-review

50 Scopus citations

Abstract

Two non-interpenetrated zirconium metal-organic frameworks (Zr-MOFs), NPF-200 and NPF-201, were synthesized via the assembly of elongated tetrahedral linkers with Zr₆ and Zr₈ clusters. They represent the first examples of MOFs to have the β-UH₃-like, 4,12,12T1 topology. Upon activation, NPF-200 exhibits the largest BET surface area (5463 m² g^-1) and void volume (81.6%) among all MOFs formed from tetrahedral ligands. Composed of negative-charged boron-centered tetrahedral linkers, NPF-201 is an anionic Zr-MOF which selectively uptakes photoactive [Ru(bpy)₃]²⁺ for heterogeneous photo-oxidation of thioanisole.

Original language	English (US)
Pages (from-to)	8380-8383
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	138
Issue number	27
DOIs	https://doi.org/10.1021/jacs.6b04608
State	Published - Jul 13 2016

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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@article{d75e32c28c264f38bbd16f899ca1f131,

title = "Highly Porous Zirconium Metal-Organic Frameworks with β-UH3-like Topology Based on Elongated Tetrahedral Linkers",

abstract = "Two non-interpenetrated zirconium metal-organic frameworks (Zr-MOFs), NPF-200 and NPF-201, were synthesized via the assembly of elongated tetrahedral linkers with Zr6 and Zr8 clusters. They represent the first examples of MOFs to have the β-UH3-like, 4,12,12T1 topology. Upon activation, NPF-200 exhibits the largest BET surface area (5463 m2 g-1) and void volume (81.6%) among all MOFs formed from tetrahedral ligands. Composed of negative-charged boron-centered tetrahedral linkers, NPF-201 is an anionic Zr-MOF which selectively uptakes photoactive [Ru(bpy)3]2+ for heterogeneous photo-oxidation of thioanisole.",

author = "Xin Zhang and Xu Zhang and Johnson, {Jacob A.} and Chen, {Yu Sheng} and Jian Zhang",

note = "Funding Information: The authors acknowledge the support from the University of Nebraska-Lincoln. ChemMatCARS Sector 15 is principally supported by the Divisions of Chemistry (CHE) and Materials Research (DMR), National Science Foundation, under grant no. NSF/CHE-1346572. Use of the APS, anOffice of Science User Facility operated for the U.S. DOE Office of Science by ANL, was supported under Contract No. DE-AC02-06CH11357. Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = jul,

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doi = "10.1021/jacs.6b04608",

language = "English (US)",

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AU - Johnson, Jacob A.

AU - Chen, Yu Sheng

AU - Zhang, Jian

N1 - Funding Information: The authors acknowledge the support from the University of Nebraska-Lincoln. ChemMatCARS Sector 15 is principally supported by the Divisions of Chemistry (CHE) and Materials Research (DMR), National Science Foundation, under grant no. NSF/CHE-1346572. Use of the APS, anOffice of Science User Facility operated for the U.S. DOE Office of Science by ANL, was supported under Contract No. DE-AC02-06CH11357. Publisher Copyright: © 2016 American Chemical Society.

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N2 - Two non-interpenetrated zirconium metal-organic frameworks (Zr-MOFs), NPF-200 and NPF-201, were synthesized via the assembly of elongated tetrahedral linkers with Zr6 and Zr8 clusters. They represent the first examples of MOFs to have the β-UH3-like, 4,12,12T1 topology. Upon activation, NPF-200 exhibits the largest BET surface area (5463 m2 g-1) and void volume (81.6%) among all MOFs formed from tetrahedral ligands. Composed of negative-charged boron-centered tetrahedral linkers, NPF-201 is an anionic Zr-MOF which selectively uptakes photoactive [Ru(bpy)3]2+ for heterogeneous photo-oxidation of thioanisole.

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