Abstract
We study the optical interband transitions of [001]-(GaP) 1(InP)m monolayer superlattices on (001) InP for m=5, 14, 27 and 51 using spectroscopic ellipsometry for photon energies from 1 to 6 eV. Samples were grown by metal-organic vapor phase epitaxy. We determine the InP-like E0, E0+Δ0, E1, E 1+Δ1, and E2 transitions from lineshape analysis of the pseudodielectric function 〈ε〉. The E0 and E0+Δ0 interband transitions depend on m due to effective alloying, strain, and symmetry reduction upon the superlattice period. Empirical pseudopotential calculations for superlattices with m=1,⋯,14 confirm the observed dependence of the E0 transition on the superlattice period. We further discuss our theoretical findings of type-II alignment for electrons and holes, which should be located within the GaP- and InP monolayers, respectively.
Original language | English (US) |
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Pages (from-to) | 125-128 |
Number of pages | 4 |
Journal | Materials Science and Engineering: B |
Volume | 88 |
Issue number | 2-3 |
DOIs | |
State | Published - Jan 16 2002 |
Externally published | Yes |
Keywords
- Band structure
- Ellipsometry
- GaP-InP-superlattice
- Ordering
ASJC Scopus subject areas
- General Materials Science
- Condensed Matter Physics
- Mechanics of Materials
- Mechanical Engineering