Iron-catalyzed enediene carbocyclizations. The total synthesis of (-)-gibboside

James M. Takacs; Suresh Vayalakkada; Steven J. Mehrman; Celia L. Kingsbury

doi:10.1016/S0040-4039(02)01662-3

Iron-catalyzed enediene carbocyclizations. The total synthesis of (-)-gibboside

James M. Takacs, Suresh Vayalakkada, Steven J. Mehrman, Celia L. Kingsbury

Chemistry

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The first total synthesis of (-)-gibboside is reported. The route features a novel iron-catalyzed carbocyclization as the key step for the construction of the cis,trans,cis-tetrasubstituted cyclopentane core.

Original language	English (US)
Pages (from-to)	8417-8420
Number of pages	4
Journal	Tetrahedron Letters
Volume	43
Issue number	46
DOIs	https://doi.org/10.1016/S0040-4039(02)01662-3
State	Published - Nov 11 2002

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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title = "Iron-catalyzed enediene carbocyclizations. The total synthesis of (-)-gibboside",

abstract = "The first total synthesis of (-)-gibboside is reported. The route features a novel iron-catalyzed carbocyclization as the key step for the construction of the cis,trans,cis-tetrasubstituted cyclopentane core.",

author = "Takacs, {James M.} and Suresh Vayalakkada and Mehrman, {Steven J.} and Kingsbury, {Celia L.}",

note = "Funding Information: Support from the NIH under grant GM34927 is gratefully acknowledged. ",

year = "2002",

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T1 - Iron-catalyzed enediene carbocyclizations. The total synthesis of (-)-gibboside

AU - Takacs, James M.

AU - Vayalakkada, Suresh

AU - Mehrman, Steven J.

AU - Kingsbury, Celia L.

N1 - Funding Information: Support from the NIH under grant GM34927 is gratefully acknowledged.

PY - 2002/11/11

Y1 - 2002/11/11

N2 - The first total synthesis of (-)-gibboside is reported. The route features a novel iron-catalyzed carbocyclization as the key step for the construction of the cis,trans,cis-tetrasubstituted cyclopentane core.

AB - The first total synthesis of (-)-gibboside is reported. The route features a novel iron-catalyzed carbocyclization as the key step for the construction of the cis,trans,cis-tetrasubstituted cyclopentane core.

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U2 - 10.1016/S0040-4039(02)01662-3

DO - 10.1016/S0040-4039(02)01662-3

M3 - Article

AN - SCOPUS:0037064472

VL - 43

SP - 8417

EP - 8420

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 46

ER -

Iron-catalyzed enediene carbocyclizations. The total synthesis of (-)-gibboside

Abstract

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