Abstract
The first total synthesis of (-)-gibboside is reported. The route features a novel iron-catalyzed carbocyclization as the key step for the construction of the cis,trans,cis-tetrasubstituted cyclopentane core.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 8417-8420 |
| Number of pages | 4 |
| Journal | Tetrahedron Letters |
| Volume | 43 |
| Issue number | 46 |
| DOIs | |
| State | Published - Nov 11 2002 |
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry
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Cite this
Takacs, J. M., Vayalakkada, S., Mehrman, S. J., & Kingsbury, C. L. (2002). Iron-catalyzed enediene carbocyclizations. The total synthesis of (-)-gibboside. Tetrahedron Letters, 43(46), 8417-8420. https://doi.org/10.1016/S0040-4039(02)01662-3