Abstract
Isomer shift data in Fe-early transition metal and Fe-metalloid amorphous systems over wide composition range have been analyzed with the Miedema-van der Woude model of isomer shift in alloys. It is found that the model gives satisfactory description in some Fe-early transition metal systems, while in the others only the general trend is predicted. In the case of Fe-metalloid systems, a large deviation from the model is always observed at the Fe-poor side. This departure, which cannot be consistently accounted for by volume mismatch mechanism, is likely to be caused by hybridization effects.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 373-376 |
| Number of pages | 4 |
| Journal | Hyperfine Interactions |
| Volume | 27 |
| Issue number | 1-4 |
| DOIs | |
| State | Published - Mar 1986 |
| Externally published | Yes |
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
- Nuclear and High Energy Physics
- Condensed Matter Physics
- Physical and Theoretical Chemistry