(Isothiocyanato)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazacyclotetradecane] copper(II) thiocyanate, [Cu(NCS)(cyclam)](SCN)

Tian Huey Lu; Tahir H. Tahirov; Yuh Liang Liu; Chung Sun Chung; Chiung Chia Huang; Yaw Shiun Hong

doi:10.1107/S0108270195016519

(Isothiocyanato)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazacyclotetradecane] copper(II) thiocyanate, [Cu(NCS)(cyclam)](SCN)

Tian Huey Lu, Tahir H. Tahirov, Yuh Liang Liu, Chung Sun Chung, Chiung Chia Huang, Yaw Shiun Hong

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The crystal structure of the title compound, [Cu(NCS)-(C₁₀H₂₄N₄)](SCN), has been determined by X-ray diffraction. A mirror plane passes through the metal atom and bisects the complex with the isothiocyanato ligand lying on the plane. The Cu^II ion is five-coordinate in a distorted square-pyramidal environment, with four amine N atoms in equatorial positions and the isothiocyanate N atom in an axial position; its coordination geometry is normal, with the equatorial Cu - N distances shorter than the axial one. The unbound SCN^- counterion is statistically disordered.

Original language	English (US)
Pages (from-to)	1093-1095
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	52
Issue number	5
DOIs	https://doi.org/10.1107/S0108270195016519
State	Published - May 15 1996
Externally published	Yes

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

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title = "(Isothiocyanato)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazacyclotetradecane] copper(II) thiocyanate, [Cu(NCS)(cyclam)](SCN)",

abstract = "The crystal structure of the title compound, [Cu(NCS)-(C10H24N4)](SCN), has been determined by X-ray diffraction. A mirror plane passes through the metal atom and bisects the complex with the isothiocyanato ligand lying on the plane. The CuII ion is five-coordinate in a distorted square-pyramidal environment, with four amine N atoms in equatorial positions and the isothiocyanate N atom in an axial position; its coordination geometry is normal, with the equatorial Cu - N distances shorter than the axial one. The unbound SCN- counterion is statistically disordered.",

author = "Lu, {Tian Huey} and Tahirov, {Tahir H.} and Liu, {Yuh Liang} and Chung, {Chung Sun} and Huang, {Chiung Chia} and Hong, {Yaw Shiun}",

year = "1996",

month = may,

day = "15",

doi = "10.1107/S0108270195016519",

language = "English (US)",

volume = "52",

pages = "1093--1095",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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T1 - (Isothiocyanato)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazacyclotetradecane] copper(II) thiocyanate, [Cu(NCS)(cyclam)](SCN)

AU - Lu, Tian Huey

AU - Tahirov, Tahir H.

AU - Liu, Yuh Liang

AU - Chung, Chung Sun

AU - Huang, Chiung Chia

AU - Hong, Yaw Shiun

PY - 1996/5/15

Y1 - 1996/5/15

N2 - The crystal structure of the title compound, [Cu(NCS)-(C10H24N4)](SCN), has been determined by X-ray diffraction. A mirror plane passes through the metal atom and bisects the complex with the isothiocyanato ligand lying on the plane. The CuII ion is five-coordinate in a distorted square-pyramidal environment, with four amine N atoms in equatorial positions and the isothiocyanate N atom in an axial position; its coordination geometry is normal, with the equatorial Cu - N distances shorter than the axial one. The unbound SCN- counterion is statistically disordered.

AB - The crystal structure of the title compound, [Cu(NCS)-(C10H24N4)](SCN), has been determined by X-ray diffraction. A mirror plane passes through the metal atom and bisects the complex with the isothiocyanato ligand lying on the plane. The CuII ion is five-coordinate in a distorted square-pyramidal environment, with four amine N atoms in equatorial positions and the isothiocyanate N atom in an axial position; its coordination geometry is normal, with the equatorial Cu - N distances shorter than the axial one. The unbound SCN- counterion is statistically disordered.

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(Isothiocyanato)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazacyclotetradecane] copper(II) thiocyanate, [Cu(NCS)(cyclam)](SCN)

Abstract

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