KINETICS AND MECHANISM OF INTERMACROMOLECULAR REACTIONS IN POLYELECTROLYTE SOLUTIONS.

Vladimir A. Izumrudov; Tatiana K. Bronich; Aleksandr B. Zezin; Viktor A. Kabanov

doi:10.1002/pol.1985.130230808

KINETICS AND MECHANISM OF INTERMACROMOLECULAR REACTIONS IN POLYELECTROLYTE SOLUTIONS.

Vladimir A. Izumrudov, Tatiana K. Bronich, Aleksandr B. Zezin, Viktor A. Kabanov

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

The kinetics of reactions were examined by the fluorescence quenching technique, polymethyl methacrylate having been used as the fluorescently tagged polyanion and poly(N-ethyl-4-vinylpyridinium bromide) (PEVP) performing as the quenching agent. The effectiveness of quenching was determined by the amount of PEVP introduced or by the composition of nonequimolar interpolyelectrolyte complexes produced. The data obtained, kinetic curves represented as conversion vs. time, demonstrate the great effect of low-molecular electrolytes on the rate of interpolyelectrolyte reactions.

Original language	English (US)
Pages (from-to)	439-444
Number of pages	6
Journal	Journal of polymer science. Polymer letters edition
Volume	23
Issue number	8
DOIs	https://doi.org/10.1002/pol.1985.130230808
State	Published - 1985
Externally published	Yes

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Engineering(all)

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abstract = "The kinetics of reactions were examined by the fluorescence quenching technique, polymethyl methacrylate having been used as the fluorescently tagged polyanion and poly(N-ethyl-4-vinylpyridinium bromide) (PEVP) performing as the quenching agent. The effectiveness of quenching was determined by the amount of PEVP introduced or by the composition of nonequimolar interpolyelectrolyte complexes produced. The data obtained, kinetic curves represented as conversion vs. time, demonstrate the great effect of low-molecular electrolytes on the rate of interpolyelectrolyte reactions.",

author = "Izumrudov, {Vladimir A.} and Bronich, {Tatiana K.} and Zezin, {Aleksandr B.} and Kabanov, {Viktor A.}",

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doi = "10.1002/pol.1985.130230808",

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AU - Izumrudov, Vladimir A.

AU - Bronich, Tatiana K.

AU - Zezin, Aleksandr B.

AU - Kabanov, Viktor A.

PY - 1985

Y1 - 1985

N2 - The kinetics of reactions were examined by the fluorescence quenching technique, polymethyl methacrylate having been used as the fluorescently tagged polyanion and poly(N-ethyl-4-vinylpyridinium bromide) (PEVP) performing as the quenching agent. The effectiveness of quenching was determined by the amount of PEVP introduced or by the composition of nonequimolar interpolyelectrolyte complexes produced. The data obtained, kinetic curves represented as conversion vs. time, demonstrate the great effect of low-molecular electrolytes on the rate of interpolyelectrolyte reactions.

AB - The kinetics of reactions were examined by the fluorescence quenching technique, polymethyl methacrylate having been used as the fluorescently tagged polyanion and poly(N-ethyl-4-vinylpyridinium bromide) (PEVP) performing as the quenching agent. The effectiveness of quenching was determined by the amount of PEVP introduced or by the composition of nonequimolar interpolyelectrolyte complexes produced. The data obtained, kinetic curves represented as conversion vs. time, demonstrate the great effect of low-molecular electrolytes on the rate of interpolyelectrolyte reactions.

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ER -

KINETICS AND MECHANISM OF INTERMACROMOLECULAR REACTIONS IN POLYELECTROLYTE SOLUTIONS.

Abstract

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