TY - JOUR
T1 - KINETICS AND MECHANISM OF INTERMACROMOLECULAR REACTIONS IN POLYELECTROLYTE SOLUTIONS.
AU - Izumrudov, Vladimir A.
AU - Bronich, Tatiana K.
AU - Zezin, Aleksandr B.
AU - Kabanov, Viktor A.
PY - 1985
Y1 - 1985
N2 - The kinetics of reactions were examined by the fluorescence quenching technique, polymethyl methacrylate having been used as the fluorescently tagged polyanion and poly(N-ethyl-4-vinylpyridinium bromide) (PEVP) performing as the quenching agent. The effectiveness of quenching was determined by the amount of PEVP introduced or by the composition of nonequimolar interpolyelectrolyte complexes produced. The data obtained, kinetic curves represented as conversion vs. time, demonstrate the great effect of low-molecular electrolytes on the rate of interpolyelectrolyte reactions.
AB - The kinetics of reactions were examined by the fluorescence quenching technique, polymethyl methacrylate having been used as the fluorescently tagged polyanion and poly(N-ethyl-4-vinylpyridinium bromide) (PEVP) performing as the quenching agent. The effectiveness of quenching was determined by the amount of PEVP introduced or by the composition of nonequimolar interpolyelectrolyte complexes produced. The data obtained, kinetic curves represented as conversion vs. time, demonstrate the great effect of low-molecular electrolytes on the rate of interpolyelectrolyte reactions.
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U2 - 10.1002/pol.1985.130230808
DO - 10.1002/pol.1985.130230808
M3 - Article
AN - SCOPUS:0022107552
VL - 23
SP - 439
EP - 444
JO - Journal of Polymer Science, Part B: Polymer Physics
JF - Journal of Polymer Science, Part B: Polymer Physics
SN - 0887-6266
IS - 8
ER -