Magnetism and structure of Fe- and Co-substituted Mn2NiSn

W. Y. Zhang, R. Skomski, S. R. Valloppilly, Y. Khatri, A. Kashyap, D. J. Sellmyer

Research output: Contribution to journalArticlepeer-review

Abstract

Mn-containing Heuslers are important magnetic shape-memory alloys for fast and precise actuators in manufacturing, robotics, surgery, and other applications. Among the key requirements are a high magnetization and favorable thermal properties, especially a high Curie temperature. In this work, the effect of Fe and Co substitution on the structure and magnetism of Mn2NiSn alloys is investigated. The Heusler alloys have been produced by melt spinning and characterized by X-ray diffraction, magnetometry, and electron-transport measurements. It was found that Co substitution for Mn enhances the Curie temperature of Mn2NiSn and both Co and Fe substitution improve its magnetization. These improvements are accompanied by reduced thermal and magnetic hysteresis losses and by interesting structural changes, namely improved chemical order and site occupancies characteristic of quaternary (Y-ordered) Heuslers.

Original languageEnglish (US)
Article number168157
JournalJournal of Magnetism and Magnetic Materials
Volume537
DOIs
StatePublished - Nov 1 2021

Keywords

  • Element substitution
  • Heusler
  • Magnetic properties
  • Structure

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

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