Metal-iodide cyclodextrins as model quasi-one-dimensional compounds

E. R. Domb; D. J. Sellmyer; G. D. Sturgeon

doi:10.1016/0022-3697(79)90156-2

Metal-iodide cyclodextrins as model quasi-one-dimensional compounds

E. R. Domb, D. J. Sellmyer, G. D. Sturgeon

Physics and Astronomy

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The synthesis and electrical and magnetic properties of two metal-iodide cyclodextrin compounds are described. Both Ba and Fe ions were added to the α-cyclodextrins to form needle-shaped single crystals. The compounds have electrical conductivities of about 10^-9 (ω cm)^-1 at room temperature. The Ba compound is diamagnetic but the Fe compound shows Curie-Weiss behavior in its susceptibility between 1.5 and 108 K, with an effective moment of 4.5 μ_B and a Weiss temperature of -5.6 K. The results indicate antiferromagnetic interactions between Fe(II) ions. A discussion is given of some problems associated with synthesizing quasi-one-dimensional conductors or magnetic compounds, using the cyclodextrins as a basis.

Original language	English (US)
Pages (from-to)	739-741
Number of pages	3
Journal	Journal of Physics and Chemistry of Solids
Volume	40
Issue number	10
DOIs	https://doi.org/10.1016/0022-3697(79)90156-2
State	Published - 1979

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Access to Document

10.1016/0022-3697(79)90156-2

Cite this

@article{0e53c026d49c49c5b1832694077724cc,

title = "Metal-iodide cyclodextrins as model quasi-one-dimensional compounds",

abstract = "The synthesis and electrical and magnetic properties of two metal-iodide cyclodextrin compounds are described. Both Ba and Fe ions were added to the α-cyclodextrins to form needle-shaped single crystals. The compounds have electrical conductivities of about 10-9 (ω cm)-1 at room temperature. The Ba compound is diamagnetic but the Fe compound shows Curie-Weiss behavior in its susceptibility between 1.5 and 108 K, with an effective moment of 4.5 μB and a Weiss temperature of -5.6 K. The results indicate antiferromagnetic interactions between Fe(II) ions. A discussion is given of some problems associated with synthesizing quasi-one-dimensional conductors or magnetic compounds, using the cyclodextrins as a basis.",

author = "Domb, {E. R.} and Sellmyer, {D. J.} and Sturgeon, {G. D.}",

note = "Funding Information: tResearch supportedb y National Science FoundationG rants DMR 7581058 and DMR 76-81603. $Pmsent address: event of Physics, Harvey Mudd Col-kge, Claremont,C A 8t711, U.S.A.",

year = "1979",

doi = "10.1016/0022-3697(79)90156-2",

language = "English (US)",

volume = "40",

pages = "739--741",

journal = "Journal of Physics and Chemistry of Solids",

issn = "0022-3697",

publisher = "Elsevier Limited",

number = "10",

}

TY - JOUR

T1 - Metal-iodide cyclodextrins as model quasi-one-dimensional compounds

AU - Domb, E. R.

AU - Sellmyer, D. J.

AU - Sturgeon, G. D.

N1 - Funding Information: tResearch supportedb y National Science FoundationG rants DMR 7581058 and DMR 76-81603. $Pmsent address: event of Physics, Harvey Mudd Col-kge, Claremont,C A 8t711, U.S.A.

PY - 1979

Y1 - 1979

N2 - The synthesis and electrical and magnetic properties of two metal-iodide cyclodextrin compounds are described. Both Ba and Fe ions were added to the α-cyclodextrins to form needle-shaped single crystals. The compounds have electrical conductivities of about 10-9 (ω cm)-1 at room temperature. The Ba compound is diamagnetic but the Fe compound shows Curie-Weiss behavior in its susceptibility between 1.5 and 108 K, with an effective moment of 4.5 μB and a Weiss temperature of -5.6 K. The results indicate antiferromagnetic interactions between Fe(II) ions. A discussion is given of some problems associated with synthesizing quasi-one-dimensional conductors or magnetic compounds, using the cyclodextrins as a basis.

AB - The synthesis and electrical and magnetic properties of two metal-iodide cyclodextrin compounds are described. Both Ba and Fe ions were added to the α-cyclodextrins to form needle-shaped single crystals. The compounds have electrical conductivities of about 10-9 (ω cm)-1 at room temperature. The Ba compound is diamagnetic but the Fe compound shows Curie-Weiss behavior in its susceptibility between 1.5 and 108 K, with an effective moment of 4.5 μB and a Weiss temperature of -5.6 K. The results indicate antiferromagnetic interactions between Fe(II) ions. A discussion is given of some problems associated with synthesizing quasi-one-dimensional conductors or magnetic compounds, using the cyclodextrins as a basis.

UR - http://www.scopus.com/inward/record.url?scp=0018711305&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0018711305&partnerID=8YFLogxK

U2 - 10.1016/0022-3697(79)90156-2

DO - 10.1016/0022-3697(79)90156-2

M3 - Article

AN - SCOPUS:0018711305

SN - 0022-3697

VL - 40

SP - 739

EP - 741

JO - Journal of Physics and Chemistry of Solids

JF - Journal of Physics and Chemistry of Solids

IS - 10

ER -

Metal-iodide cyclodextrins as model quasi-one-dimensional compounds

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this