Mild and efficient Re(VII)-catalyzed synthesis of 1,1-dihydroperoxides

Prasanta Ghorai, Patrick H. Dussault

Research output: Contribution to journalArticlepeer-review

80 Scopus citations

Abstract

(Chemical Equation Presented) Re2O7 in CH 3CN is a remarkably efficient and mild catalyst for the peroxyacetalization of ketones, aldehydes, or acetals by H2O 2 to generate 1,1-dihydroperoxides. Me3SiOReO3 and methyl rhenium trioxide (MTO) are also effective catalysts under these reaction conditions.

Original languageEnglish (US)
Pages (from-to)4577-4579
Number of pages3
JournalOrganic Letters
Volume10
Issue number20
DOIs
StatePublished - 2008

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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