TY - JOUR
T1 - Monomeric tert-butanol in benzene and cyclohexane solutions
T2 - A fourier-transform infrared spectroscopy study
AU - Larsen, Gustavo
AU - Ismail, Zohair K.
PY - 1998/10
Y1 - 1998/10
N2 - The dependence of the hydroxyl stretching frequency of monomeric tert-butanol in cyclohexane and benzene solutions on concentration was studied at different temperatures. The -OH group in the monomeric form of the alcohol appears to experience very small or negligible alcohol concentration effects. This is attributed to the ability of tert-butanol to form dimers by hydrogen bonding, which in turn shield their polar groups from monomeric tert-butanol. As a result, the environment that the latter interacts with consists of weakly polar or nonpolar species (cyclohexane or benzene), and the nonpolar (methyl) groups of dimeric tert-butanol.
AB - The dependence of the hydroxyl stretching frequency of monomeric tert-butanol in cyclohexane and benzene solutions on concentration was studied at different temperatures. The -OH group in the monomeric form of the alcohol appears to experience very small or negligible alcohol concentration effects. This is attributed to the ability of tert-butanol to form dimers by hydrogen bonding, which in turn shield their polar groups from monomeric tert-butanol. As a result, the environment that the latter interacts with consists of weakly polar or nonpolar species (cyclohexane or benzene), and the nonpolar (methyl) groups of dimeric tert-butanol.
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U2 - 10.1023/A:1022659111851
DO - 10.1023/A:1022659111851
M3 - Article
AN - SCOPUS:0041173254
VL - 27
SP - 901
EP - 909
JO - Journal of Solution Chemistry
JF - Journal of Solution Chemistry
SN - 0095-9782
IS - 10
ER -