Natural-Abundance Oxygen-17 NMR Spectra of Ozonides

F. Hock, V. Ball, Y. Dong, S. H. Gutsche, M. Hilss, K. Schlindwein, K. Griesbaum

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19 Scopus citations

Abstract

The natural-abundance 17O NMR spectra of 35 ozonides have been examined with the following results: Symmetrically tetrasubstituted ozonides and symmetrically disubstituted ozonides give only one signal each for the ether and the peroxide O atoms. Unsymmetrically tetrasubstituted ozonides bearing the electron-withdrawing groups CI, CN, or CF3, and also some unsymmetrically disubstituted ozonides, give two signals for the per oxide O atoms. Electron-withdrawing groups and ring stress in bicyclic ozonides cause downfield shifts in the -O-O- signals and even larger ones in the -O- signals. The range in which the signals appeared was 87-172 ppm for the ether O atoms and 263-336 ppm for the peroxide O atoms.

Original languageEnglish (US)
Pages (from-to)150-154
Number of pages5
JournalJournal of Magnetic Resonance, Series A
Volume111
Issue number2
DOIs
StatePublished - 1994
Externally publishedYes

ASJC Scopus subject areas

  • Engineering(all)

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