Natural Uranium Contamination in Major U.S. Aquifers Linked to Nitrate

Jason Nolan, Karrie A. Weber

Research output: Contribution to journalArticle

83 Scopus citations

Abstract

Groundwater geochemical data collected from two major U.S. aquifers, High Plains (HP) and Central Valley (CV), revealed naturally occurring groundwater uranium (U) exceeding the U.S. Environmental Protection Agency maximum contaminant level (MCL = 30 μg/L) across 22375 km2 where 1.9 million people live. Analysis of geochemical parameters revealed a moderately strong correlation between U and nitrate, a common groundwater contaminant, as well as alkalinity and calcium [Spearman's rho (ρ) ≥ 0.30; p < 0.001]. Nitrate is recognized to alter U solubility by oxidative dissolution of reduced U(IV) minerals. Approximately 78% of areas where U concentrations were interpolated above the MCL were correlated to the presence of nitrate (Pearson's r ≥ 0.5; p < 0.05). Shallow groundwater was determined to be the most susceptible to co-contamination (HP, ρ = 0.46; CV, ρ = 0.52). Together, these results indicate that nitrate, a primary contaminant, should be considered as a factor leading to secondary groundwater U contamination in addition to the recognized role of alkalinity and calcium.

Original languageEnglish (US)
Pages (from-to)215-220
Number of pages6
JournalEnvironmental Science and Technology Letters
Volume2
Issue number8
DOIs
StatePublished - Aug 11 2015

ASJC Scopus subject areas

  • Environmental Chemistry
  • Ecology
  • Water Science and Technology
  • Waste Management and Disposal
  • Pollution
  • Health, Toxicology and Mutagenesis

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