Odorous VOC emission following land application of swine manure slurry

David B. Parker, John Gilley, Bryan Woodbury, Ki Hyun Kim, Geordie Galvin, Shannon L. Bartelt-Hunt, Xu Li, Daniel D. Snow

Research output: Contribution to journalArticlepeer-review

67 Scopus citations

Abstract

Swine manure is often applied to crop land as a fertilizer source. Odor emissions from land-applied swine manure may pose a nuisance to downwind populations if manure is not applied with sufficient forethought. A research project was conducted to assess the time decay of odorous volatile organic compound (VOC) emissions following land application of swine manure. Three land application methods were compared: surface application, incorporation 24 h after surface application, and injection. Emission rates were measured in field plots using a small wind tunnel and sorbent tubes. VOCs including eight volatile fatty acids, five aromatics, and two sulfur-containing compounds were quantified by gas chromatography-mass spectrometry. In most cases, a first order exponential decay model adequately described the flux versus time relationship for the 24 h period following land application, but the model sometimes overestimated flux in the 6-24 h range. The same model but with the time term squared adequately predicted flux over the entire 24 h period. Three compounds (4-methylphenol, skatole, and 4-ethylphenol) accounted for 93 percent of the summed odor activity value. First order decay constants (k) for these three compounds ranged from 0.157 to 0.996 h-1. When compared to surface application, injection of swine manure resulted in 80-95 percent lower flux for the most odorous aromatic compounds. These results show that VOC flux decreases rapidly following land application of swine manure, declining below levels of detection and near background levels after 4 to 8 h.

Original languageEnglish (US)
Pages (from-to)91-100
Number of pages10
JournalAtmospheric Environment
Volume66
DOIs
StatePublished - Feb 2013

Keywords

  • Air quality
  • Manure
  • Odor
  • Swine
  • Volatile organic compound

ASJC Scopus subject areas

  • Environmental Science(all)
  • Atmospheric Science

Fingerprint Dive into the research topics of 'Odorous VOC emission following land application of swine manure slurry'. Together they form a unique fingerprint.

Cite this