Ozonolyses of O‐methyloximes in the presence of acid derivatives: A new access to substituted ozonides

Karl Griesbaum, Bikem Övez, Tae Sung Huh, Yuxiang Dong

Research output: Contribution to journalArticle

25 Scopus citations

Abstract

Ozonolyses of O‐methyloximes (4) of 5‐, 6‐ and 7‐membered cycloketones in the presence of esters of trifluoroacetic acid (5) or of acyl cyanides (6) afforded ozonides of types 7 and 8, respectively, which are formally derived from vinyl ethers or vinyl cyanides. Similarly, ozonolysis of the O‐methylated oxime of acetone (9) in the presence of esters of trifluoroacetic acid (5) and of the O‐methylated oxime of 2‐naphthaldehyde (11) in the presence of acyl cyanides (6) gave the corresponding ozonides of types 10 and 12, respectively.

Original languageEnglish (US)
Pages (from-to)1571-1574
Number of pages4
JournalLiebigs Annalen
Volume1995
Issue number8
DOIs
StatePublished - Jul 24 1995

Keywords

  • Oximes
  • Ozonides, substituted
  • Ozonolysis
  • O‐methylated

ASJC Scopus subject areas

  • Chemistry(all)

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