Pentafluorophenyl transfer reaction: Preparation of pentafluorophenyl [60]fullerene adducts through opening of fullerene epoxide moiety with trispentafluorophenylborane

Sisi Liang; Liang Xu; Zhenshan Jia; Liangbing Gan

doi:10.1021/jo5009228

Pentafluorophenyl transfer reaction: Preparation of pentafluorophenyl [60]fullerene adducts through opening of fullerene epoxide moiety with trispentafluorophenylborane

Sisi Liang, Liang Xu, Zhenshan Jia, Liangbing Gan

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Unlike the extensively studied perfluoroalkyl fullerene adducts, perfluorophenyl fullerene adducts are quite difficult to prepare by known methods. Trispentafluorophenylborane was found to react with fullerene epoxide to form the 1,2-perfluorophenylfullerenol. The method can be applied to both the simple epoxide C₆₀(O) and fullerene multiadducts containing an epoxide moiety. Single crystal X-ray structure analysis confirmed the addition of the pentafluorophenyl group.

Original language	English (US)
Pages (from-to)	5794-5798
Number of pages	5
Journal	Journal of Organic Chemistry
Volume	79
Issue number	12
DOIs	https://doi.org/10.1021/jo5009228
State	Published - Jun 20 2014
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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title = "Pentafluorophenyl transfer reaction: Preparation of pentafluorophenyl [60]fullerene adducts through opening of fullerene epoxide moiety with trispentafluorophenylborane",

abstract = "Unlike the extensively studied perfluoroalkyl fullerene adducts, perfluorophenyl fullerene adducts are quite difficult to prepare by known methods. Trispentafluorophenylborane was found to react with fullerene epoxide to form the 1,2-perfluorophenylfullerenol. The method can be applied to both the simple epoxide C60(O) and fullerene multiadducts containing an epoxide moiety. Single crystal X-ray structure analysis confirmed the addition of the pentafluorophenyl group.",

author = "Sisi Liang and Liang Xu and Zhenshan Jia and Liangbing Gan",

year = "2014",

month = jun,

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doi = "10.1021/jo5009228",

language = "English (US)",

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T1 - Pentafluorophenyl transfer reaction

T2 - Preparation of pentafluorophenyl [60]fullerene adducts through opening of fullerene epoxide moiety with trispentafluorophenylborane

AU - Liang, Sisi

AU - Xu, Liang

AU - Jia, Zhenshan

AU - Gan, Liangbing

PY - 2014/6/20

Y1 - 2014/6/20

N2 - Unlike the extensively studied perfluoroalkyl fullerene adducts, perfluorophenyl fullerene adducts are quite difficult to prepare by known methods. Trispentafluorophenylborane was found to react with fullerene epoxide to form the 1,2-perfluorophenylfullerenol. The method can be applied to both the simple epoxide C60(O) and fullerene multiadducts containing an epoxide moiety. Single crystal X-ray structure analysis confirmed the addition of the pentafluorophenyl group.

AB - Unlike the extensively studied perfluoroalkyl fullerene adducts, perfluorophenyl fullerene adducts are quite difficult to prepare by known methods. Trispentafluorophenylborane was found to react with fullerene epoxide to form the 1,2-perfluorophenylfullerenol. The method can be applied to both the simple epoxide C60(O) and fullerene multiadducts containing an epoxide moiety. Single crystal X-ray structure analysis confirmed the addition of the pentafluorophenyl group.

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IS - 12

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Pentafluorophenyl transfer reaction: Preparation of pentafluorophenyl [60]fullerene adducts through opening of fullerene epoxide moiety with trispentafluorophenylborane

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