Peroxides of Sterically Hindered Derivatives of Schlenk Hydrocarbon Diradical

Andrzej Rajca, Suchada Rajca, Shailesh R. Desai, Victor W. Day

Research output: Contribution to journalArticle

11 Scopus citations

Abstract

Reaction of oxygen with three sterically hindered derivatives of Schlenk hydrocarbon diradical gives predominantly cyclic peroxides with cross-conjugated π-systems. For mesitylene-based diradical 3, significantly different yields of the cyclic peroxide for the reactions in the solid state vs solution were obtained. In the absence of crystallographic studies for Schlenk hydrocarbon and its derivatives, X-ray crystallography for peroxide 1A-O2 supports the structural assignment for the corresponding diradicals.

Original languageEnglish (US)
Pages (from-to)6524-6528
Number of pages5
JournalJournal of Organic Chemistry
Volume62
Issue number19
DOIs
StatePublished - 1997

ASJC Scopus subject areas

  • Organic Chemistry

Fingerprint Dive into the research topics of 'Peroxides of Sterically Hindered Derivatives of Schlenk Hydrocarbon Diradical'. Together they form a unique fingerprint.

  • Cite this