Quantitative Analysis of Manganese in Low Alloy Steel with Micro-Laser-Induced Breakdown Spectroscopy

Xu Zhao Wang; Zhong Qi Hao; Lian Bo Guo; Xiang You Li; Xiao Yan Zeng; Yong Feng Lu

doi:10.3964/j.issn.1000-0593(2017)04-1254-05

Quantitative Analysis of Manganese in Low Alloy Steel with Micro-Laser-Induced Breakdown Spectroscopy

Xu Zhao Wang, Zhong Qi Hao, Lian Bo Guo, Xiang You Li, Xiao Yan Zeng, Yong Feng Lu

Research output: Contribution to journal › Article

2 Scopus citations

Abstract

Manganese in the low alloy steel was analyzed quantitatively using micro-laser-induced breakdown spectroscopy. The spatial resolution of 20 μm and the single pulse limit of detection of 0.10% were obtained. The calibration curve of Mn was established with basic calibration method, with determination coefficient (R²) of 0.97. The average relative error of Mn concentration prediction on 7 samples is 12.91%, and the root-mean-square error of cross-validation (RMSECV) is 0.11%. The R² reaches 0.99 when using internal calibration method, as well as the average relative error of Mn concentration prediction on 7 samples and RMSECV were decreased to 7.25% and 0.07%, respectively. These results show that MicroLIBS technique is an effective approach for material surfaces quantitative microanalysis.

Original language	English (US)
Pages (from-to)	1254-1258
Number of pages	5
Journal	Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis
Volume	37
Issue number	4
DOIs	https://doi.org/10.3964/j.issn.1000-0593(2017)04-1254-05
State	Published - Apr 1 2017
Externally published	Yes

Keywords

Laser-induced breakdown spectroscopy
Microscope optics
Mn
Quantitative analysis

ASJC Scopus subject areas

Instrumentation
Spectroscopy

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Wang, X. Z., Hao, Z. Q., Guo, L. B., Li, X. Y., Zeng, X. Y., & Lu, Y. F. (2017). Quantitative Analysis of Manganese in Low Alloy Steel with Micro-Laser-Induced Breakdown Spectroscopy. Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis, 37(4), 1254-1258. https://doi.org/10.3964/j.issn.1000-0593(2017)04-1254-05

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title = "Quantitative Analysis of Manganese in Low Alloy Steel with Micro-Laser-Induced Breakdown Spectroscopy",

abstract = "Manganese in the low alloy steel was analyzed quantitatively using micro-laser-induced breakdown spectroscopy. The spatial resolution of 20 μm and the single pulse limit of detection of 0.10% were obtained. The calibration curve of Mn was established with basic calibration method, with determination coefficient (R2) of 0.97. The average relative error of Mn concentration prediction on 7 samples is 12.91%, and the root-mean-square error of cross-validation (RMSECV) is 0.11%. The R2 reaches 0.99 when using internal calibration method, as well as the average relative error of Mn concentration prediction on 7 samples and RMSECV were decreased to 7.25% and 0.07%, respectively. These results show that MicroLIBS technique is an effective approach for material surfaces quantitative microanalysis.",

keywords = "Laser-induced breakdown spectroscopy, Microscope optics, Mn, Quantitative analysis",

author = "Wang, {Xu Zhao} and Hao, {Zhong Qi} and Guo, {Lian Bo} and Li, {Xiang You} and Zeng, {Xiao Yan} and Lu, {Yong Feng}",

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T1 - Quantitative Analysis of Manganese in Low Alloy Steel with Micro-Laser-Induced Breakdown Spectroscopy

AU - Wang, Xu Zhao

AU - Hao, Zhong Qi

AU - Guo, Lian Bo

AU - Li, Xiang You

AU - Zeng, Xiao Yan

AU - Lu, Yong Feng

PY - 2017/4/1

Y1 - 2017/4/1

N2 - Manganese in the low alloy steel was analyzed quantitatively using micro-laser-induced breakdown spectroscopy. The spatial resolution of 20 μm and the single pulse limit of detection of 0.10% were obtained. The calibration curve of Mn was established with basic calibration method, with determination coefficient (R2) of 0.97. The average relative error of Mn concentration prediction on 7 samples is 12.91%, and the root-mean-square error of cross-validation (RMSECV) is 0.11%. The R2 reaches 0.99 when using internal calibration method, as well as the average relative error of Mn concentration prediction on 7 samples and RMSECV were decreased to 7.25% and 0.07%, respectively. These results show that MicroLIBS technique is an effective approach for material surfaces quantitative microanalysis.

AB - Manganese in the low alloy steel was analyzed quantitatively using micro-laser-induced breakdown spectroscopy. The spatial resolution of 20 μm and the single pulse limit of detection of 0.10% were obtained. The calibration curve of Mn was established with basic calibration method, with determination coefficient (R2) of 0.97. The average relative error of Mn concentration prediction on 7 samples is 12.91%, and the root-mean-square error of cross-validation (RMSECV) is 0.11%. The R2 reaches 0.99 when using internal calibration method, as well as the average relative error of Mn concentration prediction on 7 samples and RMSECV were decreased to 7.25% and 0.07%, respectively. These results show that MicroLIBS technique is an effective approach for material surfaces quantitative microanalysis.

KW - Laser-induced breakdown spectroscopy

KW - Microscope optics

KW - Mn

KW - Quantitative analysis

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