Recent advances in visible-light-driven carbon dioxide reduction by metal-organic frameworks

Metal-organic frameworks (MOFs) have emerged as promising materials and have attracted researchers due to their unique chemical and physical properties—design flexibility, tuneable pore channels, a high surface-to-volume ratio that allow their distinct application in diverse research fields—gas storage, gas separation, catalysis, adsorption, drug delivery, ion exchange, sensing, etc. The rapidly growing CO₂ in the atmosphere is a global concern due to the excessive use of fossil fuels in the current era. CO₂ is the prime cause of global warming and should be ameliorated either through adsorption or conversion into value-added products to protect the environment and mankind. Nowadays, MOFs are exploited as a photocatalyst for applications of CO₂ reduction. Since the use of semiconductors limits the use of visible light for photocatalytic reduction of CO₂, MOFs are promising options. The current review describes recent development in the application of MOFs as host, composites, and their derivatives in photocatalytic reduction of CO₂ to CO and different organic chemicals (HCOOH, CH₃OH, CH₄). Efficient charge separation and visible light absorption by incorporation of active sites for efficient photocatalysis have been discussed. The selection of material for high CO₂ uptake and potential strategies for the rational design and development of high-performance catalysts are outlined. Major challenges and future perspectives have also been discussed at the last of the review.