Ruthenium-Catalyzed Amination of Secondary Alcohols Using Borrowing Hydrogen Methodology

Kostiantyn O. Marichev; James M. Takacs

doi:10.1021/acscatal.6b00175

Ruthenium-Catalyzed Amination of Secondary Alcohols Using Borrowing Hydrogen Methodology

Kostiantyn O. Marichev, James M. Takacs

Chemistry

Research output: Contribution to journal › Article › peer-review

96 Scopus citations

Abstract

A new ruthenium complex catalyzes the amination of primary and secondary alcohols and the regioselective mono- and sequential diamination of diols via the borrowing hydrogen pathway. Several variations on new intra- and intermolecular cyclizations of aminoalcohols, diols, and diamines lead to heterocyclic ring systems.

Original language	English (US)
Pages (from-to)	2205-2210
Number of pages	6
Journal	ACS Catalysis
Volume	6
Issue number	4
DOIs	https://doi.org/10.1021/acscatal.6b00175
State	Published - Apr 1 2016

Keywords

aminations
borrowing hydrogen
heterocycle synthesis
hydrogen autotransfer
ruthenium(II) complex

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1021/acscatal.6b00175

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abstract = "A new ruthenium complex catalyzes the amination of primary and secondary alcohols and the regioselective mono- and sequential diamination of diols via the borrowing hydrogen pathway. Several variations on new intra- and intermolecular cyclizations of aminoalcohols, diols, and diamines lead to heterocyclic ring systems.",

keywords = "aminations, borrowing hydrogen, heterocycle synthesis, hydrogen autotransfer, ruthenium(II) complex",

author = "Marichev, {Kostiantyn O.} and Takacs, {James M.}",

note = "Funding Information: Financial support from the NIH (NIGMS R01 GM100101) is gratefully acknowledged. Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

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N2 - A new ruthenium complex catalyzes the amination of primary and secondary alcohols and the regioselective mono- and sequential diamination of diols via the borrowing hydrogen pathway. Several variations on new intra- and intermolecular cyclizations of aminoalcohols, diols, and diamines lead to heterocyclic ring systems.

AB - A new ruthenium complex catalyzes the amination of primary and secondary alcohols and the regioselective mono- and sequential diamination of diols via the borrowing hydrogen pathway. Several variations on new intra- and intermolecular cyclizations of aminoalcohols, diols, and diamines lead to heterocyclic ring systems.

KW - aminations

KW - borrowing hydrogen

KW - heterocycle synthesis

KW - hydrogen autotransfer

KW - ruthenium(II) complex

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ER -

Ruthenium-Catalyzed Amination of Secondary Alcohols Using Borrowing Hydrogen Methodology

Abstract

Keywords

ASJC Scopus subject areas

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