Abstract
A new ruthenium complex catalyzes the amination of primary and secondary alcohols and the regioselective mono- and sequential diamination of diols via the borrowing hydrogen pathway. Several variations on new intra- and intermolecular cyclizations of aminoalcohols, diols, and diamines lead to heterocyclic ring systems.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 2205-2210 |
| Number of pages | 6 |
| Journal | ACS Catalysis |
| Volume | 6 |
| Issue number | 4 |
| DOIs | |
| State | Published - Apr 1 2016 |
Keywords
- aminations
- borrowing hydrogen
- heterocycle synthesis
- hydrogen autotransfer
- ruthenium(II) complex
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
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Cite this
Marichev, K. O., & Takacs, J. M. (2016). Ruthenium-Catalyzed Amination of Secondary Alcohols Using Borrowing Hydrogen Methodology. ACS Catalysis, 6(4), 2205-2210. https://doi.org/10.1021/acscatal.6b00175