SnCl4-mediated reaction of ozonides with allyltrimethylsilane: Formation of 1,2-dioxolanes

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Abstract

SnC14-mediated reaction of ozonides (1,2,4-trioxolanes) with allyltrimethylsilane furnishes trimethylsilylmethyl-1,2-dioxolanes via metalated carbonyl oxides. The carbonyl oxides can arise through initial ionization of either the ether or peroxide oxygens.

Original languageEnglish (US)
Pages (from-to)6553-6556
Number of pages4
JournalTetrahedron Letters
Volume40
Issue number36
DOIs
StatePublished - Sep 3 1999

Keywords

  • Allylation
  • Dioxolanes
  • Ozonides
  • Peroxides

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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