Spiro oligothiophenes

Makoto Miyasaka, Maren Pink, Suchada Rajca, Andrzej Rajca

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

(Figure Presented) Linear oligothiophenes, containing annelated dithieno[2,3-b:3′,2′-d]thiophene units, undergo unexpected spirocyclizations upon treatment with trifluoroacetic acid. The resultant spiro oligothiophenes possess novel structures in which the spiro or dispiro skeleton is within an all-thiophene/dihydrothiophene framework. Racemic dispiro octathiophene is obtained with high diastereoselectivity and in high yield.

Original languageEnglish (US)
Pages (from-to)3230-3233
Number of pages4
JournalOrganic Letters
Volume12
Issue number14
DOIs
StatePublished - Jul 16 2010

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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