Strong aggregation and directional assembly of aromatic oligoamide macrocycles

Yongan Yang, Wen Feng, Jinchuan Hu, Shuliang Zou, Rongzhao Gao, Kazuhiro Yamato, Mark Kline, Zhonghou Cai, Yi Gao, Yibing Wang, Yibao Li, Yanlian Yang, Lihua Yuan, Xiao Cheng Zeng, Bing Gong

Research output: Contribution to journalArticlepeer-review

80 Scopus citations

Abstract

Aromatic oligoamide macrocycles exhibit strong preference for highly directional association. Aggregation happens in both nonpolar and polar solvents but is weakened as solvent polarity increases. The strong, directional assembly is rationalized by the cooperative action of dipole-dipole and π-π stacking interactions, leading to long nanotubular assemblies that are confirmed by SEM, TEM, AFM, and XRD. The persistent nanotubular assemblies contain non-collapsible hydrophilic internal pores that mediate highly efficient ion transport observed with these macrocycles and serve as cylindrical sites for accommodating guests such as metal ions.

Original languageEnglish (US)
Pages (from-to)18590-18593
Number of pages4
JournalJournal of the American Chemical Society
Volume133
Issue number46
DOIs
StatePublished - Nov 23 2011

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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