Synthesis and characterization of a trigonal bipyramidal supramolecular cage based upon rhodium and platinum metal centers

Jered C. Garrison; Matthew J. Panzner; Paul D. Custer; D. Venkat Reddy; Peter L. Rinaldi; Claire A. Tessier; Wiley J. Youngs

doi:10.1039/b608991g

Synthesis and characterization of a trigonal bipyramidal supramolecular cage based upon rhodium and platinum metal centers

Jered C. Garrison, Matthew J. Panzner, Paul D. Custer, D. Venkat Reddy, Peter L. Rinaldi, Claire A. Tessier, Wiley J. Youngs

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

The reaction of 4-ethynyl-pyridine with tert-butyl lithium followed by its addition to (Me₃tacn)RhCl₃ affords the facial octahedral complex (Me₃tacn)Rh(CCPy)₃, condensation of which with the square planar complex cis-(DCPE)Pt(NO₃)₂ results in a self-assembled trigonal bipyramidal cage with Rh(iii) and Pt(ii) atoms occupying the vertices.

Original language	English (US)
Pages (from-to)	4644-4646
Number of pages	3
Journal	Chemical Communications
Issue number	44
DOIs	https://doi.org/10.1039/b608991g
State	Published - 2006
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b608991g

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title = "Synthesis and characterization of a trigonal bipyramidal supramolecular cage based upon rhodium and platinum metal centers",

abstract = "The reaction of 4-ethynyl-pyridine with tert-butyl lithium followed by its addition to (Me3tacn)RhCl3 affords the facial octahedral complex (Me3tacn)Rh(CCPy)3, condensation of which with the square planar complex cis-(DCPE)Pt(NO3)2 results in a self-assembled trigonal bipyramidal cage with Rh(iii) and Pt(ii) atoms occupying the vertices.",

author = "Garrison, {Jered C.} and Panzner, {Matthew J.} and Custer, {Paul D.} and Reddy, {D. Venkat} and Rinaldi, {Peter L.} and Tessier, {Claire A.} and Youngs, {Wiley J.}",

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doi = "10.1039/b608991g",

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journal = "Chemical Communications",

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T1 - Synthesis and characterization of a trigonal bipyramidal supramolecular cage based upon rhodium and platinum metal centers

AU - Garrison, Jered C.

AU - Panzner, Matthew J.

AU - Custer, Paul D.

AU - Reddy, D. Venkat

AU - Rinaldi, Peter L.

AU - Tessier, Claire A.

AU - Youngs, Wiley J.

PY - 2006

Y1 - 2006

N2 - The reaction of 4-ethynyl-pyridine with tert-butyl lithium followed by its addition to (Me3tacn)RhCl3 affords the facial octahedral complex (Me3tacn)Rh(CCPy)3, condensation of which with the square planar complex cis-(DCPE)Pt(NO3)2 results in a self-assembled trigonal bipyramidal cage with Rh(iii) and Pt(ii) atoms occupying the vertices.

AB - The reaction of 4-ethynyl-pyridine with tert-butyl lithium followed by its addition to (Me3tacn)RhCl3 affords the facial octahedral complex (Me3tacn)Rh(CCPy)3, condensation of which with the square planar complex cis-(DCPE)Pt(NO3)2 results in a self-assembled trigonal bipyramidal cage with Rh(iii) and Pt(ii) atoms occupying the vertices.

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JO - Chemical Communications

JF - Chemical Communications

IS - 44

ER -

Synthesis and characterization of a trigonal bipyramidal supramolecular cage based upon rhodium and platinum metal centers

Abstract

ASJC Scopus subject areas

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